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author:

Gao, S.-K. (Gao, S.-K..) [1] | Wang, G.-M. (Wang, G.-M..) [2] | Jiang, Y.-X. (Jiang, Y.-X..) [3] | Chen, J.-Z. (Chen, J.-Z..) [4]

Indexed by:

Scopus PKU CSCD

Abstract:

The nucleation of ammonium tetramolybdate in supersaturated solutions prepared by HCl and HNO3 was studied respectively under temperatures from 295.15 K to 311.15 K at different levels of supersaturation. Effects of temperature and supersaturation on the induction period of ammonium tetramolybdate were discussed. According to classical nucleation theory, it was possible to distinguish the homogeneous and heterogeneous nucleation from the influence of temperature and supersaturation on induction, period. The interfacial tension, critical radius and critical Gibbs free energy of formation of the crystal nuclei were estimated. Differences of homogeneous nucleation rate of ammonium tetramolybdate in solutions prepared by HCl and HNO3 were discussed.

Keyword:

Ammonium tetramolybdate; Induction period; Nucleation; Supersaturation

Community:

  • [ 1 ] [Gao, S.-K.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Wang, G.-M.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Jiang, Y.-X.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Chen, J.-Z.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Gao, S.-K.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Synthetic Crystals

ISSN: 1000-985X

Year: 2006

Issue: 6

Volume: 35

Page: 1232-1237

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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