Hydrothermal synthesis of a new open-framework zinc phosphate containing 20-ring channels - Details

author：

Zeng, Q.-X. (Zeng, Q.-X..) ^[1] | Xiang, Y. (Xiang, Y..) ^[2] | Zhang, L.-W. (Zhang, L.-W..) ^[3] | Chen, W.-H. (Chen, W.-H..) ^[4] | Chen, J.-Z. (Chen, J.-Z..) ^[5]

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Abstract：

A　new　organically　templated　open-framework　zinc　phosphate,　[C6N3H18]3+[Zn4(PO4)(HPO4)4]3-　·　2H2O,　has　been　synthesized　under　hydrothermal　conditions.　The　structure　was　determined　by　single-crystal　X-ray　diffraction.　It　crystallizes　in　the　triclinic　system,　space　group　P-1　(No.　2),　a　=　8.2130(6),　b　=　10.0257(7),　c　=　15.5133(7)　Å,　α　=　80.842(3),　β　=　75.671(4),　γ　=　89.020(5)°,　V　=　1221.54(14)　Å3,　Z　=　2.　The　tetrahedral　linkages　between　ZnO4,　PO4　and　HPO4　moieties　have　resulted　in　a　complex　three-dimensional　network　encapsulating　extra-framework　1-(2-aminoethyl)piperazine　and　water　molecules.　The　framework　is　characterized　by　the　extra-large　20-ring　channels　running　along　the　[1　0　0]　direction.　©　2006　Elsevier　Inc.　All　rights　reserved.

Keyword：

Crystal structure; Extra-large channel; Open framework; Phosphate; Zinc

Community：

[ 1 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Xiang, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Zhang, L.-W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Chen, W.-H.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 5 ] [Chen, J.-Z.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

zengqx_2004@yahoo.com.cn

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Source ：

Microporous and Mesoporous Materials

ISSN： 1387-1811

Year： 2006

Issue： 1-3

Volume： 93

Page： 270-274

2 . 7 9 6

JCR@2006

4 . 8 0 0

JCR@2023

JCR Journal Grade：1

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WoS CC Cited Count：

SCOPUS Cited Count： 4

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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