Synthesis and characterization of two silver iodides with one- and three-dimensional hybrid structures constructed from Ag⋯Ag interactions and organic templates - Details

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Abstract：

Two　new　organically　templated　silver　iodides,　namely　[(bmph)(Ag　5I7)]n　(1)　and　[(Hteda)4(Ag　12I16)]n　(2),　have　been　synthesized　with　bmph2+　and　teda　[bmph2+　=　1,6-bis(4-methylpyridinio)　hexane,　Hteda　=　protonated　triethylenediamine]　as　structure-directing　agents.　Complex　1　consists　of　a　one-dimensional　polymer　that　can　be　described　as　edge-sharing　AgI4　tetrahedra,　whereas　2　is　the　first　example　of　a　three-dimensional　Ag/I　framework　based　on　Ag⋯Ag　weak　interactions　and　an　organic　template.　Electrostatic　interactions　between　the　organic　countercations　and　inorganic　moieties　are　present　and　contribute　to　the　crystal　packing.　Both　compounds　have　been　further　characterized　by　IR　spectroscopy,　elemental　analysis,　TGA,　and　optical　limiting　measurements.　©　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　2006.

Keyword：

Coordination polymers; Iodine; Organic-inorganic hybrid composites; Silver

Community：

[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Li, J.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Li, J.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou 350002, China
[ 5 ] [Huang, C.-C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Zhang, Y.-F.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
[ 7 ] [Jia, G.-X.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Li, J.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

jqli@fzu.edu.cn

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Source ：

European Journal of Inorganic Chemistry

ISSN： 1434-1948

Year： 2006

Issue： 12

Page： 2447-2453

2 . 7 0 4

JCR@2006

2 . 2 0 0

JCR@2023

JCR Journal Grade：2

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WoS CC Cited Count：

SCOPUS Cited Count： 85

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 3

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