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Abstract:
The title complex, [Zn(C18H12N2)(C 8H4O4)]n, consists of a one-dimensional zigzag [Zn(tpa)(quin)]n chain (tpa = terephthalate and quin = 2,2′-diquinolyl) with a pitch of 17.907(2). The tpa ligands bridge two Zn atoms in alternately bis(bidentate) and bis(monodentate) coordination modes. Each Zn atom is coordinated by two N atoms from a chelating quin, two O atoms from one bis(bidentate) tpa and one O atom from one bis(monodentate) tpa. The five-coordinate Zn geometry can be best described as distorted trigonal-bipyramidal. © 2006 International Union of Crystallography. All rights reserved.
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Acta Crystallographica Section E: Structure Reports Online
ISSN: 1600-5368
Year: 2006
Issue: 5
Volume: 62
Page: m1048-m1050
0 . 5 6 7
JCR@2006
0 . 3 4 7
JCR@2011
JCR Journal Grade:4
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