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author:

Xiao, Z.-J. (Xiao, Z.-J..) [1] | Liu, S.-X. (Liu, S.-X..) [2]

Indexed by:

Scopus PKU CSCD

Abstract:

The cobalt(III) violurato complex ([Co(C4H2N 3O4)3]-6H2O, Mr = 635.28) has been prepared and structurally characterized. The crystal is of monoclinic, space group P21/n with a = 10.176(1), b = 11.8010(9), c = 19.706(2) Å, β = 97.382(3)°, V= 2346.9(4) Å3, Z = 4, Dc= 1.798 g/cm3, F(000) = 1296, μ= 0.839 mm -1, R = 0.0482 and wR = 0.1357. The Co atom in the title compound is six- coordinated by three carbonyl O atoms and three oximido N atoms of three violurato ligands, forming an octahedral coordination geometry. The neighboring molecules are connected together by hydrogen bonds of N-H⋯O, O-H⋯O and O-H⋯N, forming an extended three-dimensional supra- molecular architecture.

Keyword:

Co(III) complex; Crystal structure; Hydrogen bond; Violuric acid

Community:

  • [ 1 ] [Xiao, Z.-J.]Central Laboratory, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Xiao, Z.-J.]College of Materials Science and Engineering, Huaqiao University, Quanzhou 362011, China
  • [ 3 ] [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Liu, S.-X.]State Key Laboratory of Structural Chemistry, Fuzhou 350002, China

Reprint 's Address:

  • 刘世雄

    [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou 350002, China

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2006

Issue: 2

Volume: 25

Page: 163-167

0 . 7 2 9

JCR@2006

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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