Synthesis and characterization of a new layered zinc phosphite (NH 4)[{Zn(H2O)4}0.5Zn 2(HPO3)3] - Details

author：

Zeng, Q.-X. (Zeng, Q.-X..) ^[1] | Ke, R.-R. (Ke, R.-R..) ^[2] | Xiang, Y. (Xiang, Y..) ^[3] | Zhang, X.-W. (Zhang, X.-W..) ^[4]

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Abstract：

A　new　layered　zinc　phosphite　with　the　formula　(NH4)[{Zn(H　2O)4}0.5Zn2(HPO3)　3]　has　been　synthesized　under　hydrothermal　conditions.　Its　structure　was　determined　by　single-crystal　X-ray　diffraction.　The　compound　crystallizes　in　the　triclinic　system;　space　group　P1　(No.　2),　a　=　7.2507(4),　b　=　9.7982(6),　c　=　10.2642(6)　Å,　α　=　63.425(2),　β　=　87.165(2),　γ　=　72.999(3)°,　V　=　620.84(6)　Å3,　Z　=　2.　The　connectivity　of　ZnO4　tetrahedra,　HPO3　pseudo　pyramids　and　ZnO　2(H2O)4　octahedra　results　in　macroanionic　layers　with　4.8　net.　©　2005　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA.

Keyword：

Crystal elucidation; Hydrothermal synthesis; Layer; Phosphite; Zinc

Community：

[ 1 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 2 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Ke, R.-R.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 4 ] [Xiang, Y.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 5 ] [Zhang, X.-W.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China

Reprint 's Address：

[Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China

Email：

zengqx2004@yahoo.com.cn

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2005

Issue： 15

Volume： 631

Page： 3066-3069

1 . 2 0 2

JCR@2005

1 . 1 0 0

JCR@2023

JCR Journal Grade：3

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