Synthesis and crystal structure of a new organic-inorganic hybrid one-dimensional polymer: [Zn(C8H23N5)] 2(Pb3I10) - Details

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Abstract：

A　new　organic-inorganic　hybrid　coordinated　polymer　[Zn(C8H　23N5)]2(Pb3I10)　(C　8H23N5　=　tetraethylene　pentamine)　was　synthesized　by　hydrothermal　reaction.　It　crystallizes　in　triclinic,　space　group　P1　with　a　=　9.781(2),　b　=　11.442(3),　c　=　11.565(3)　Å,　α　=　99.075(8),　β　=　90.540(9),　γ　=　109.967(5)°,　Zn2C　16H46N10Pb3I10,　M　r　=　2399.94,　V　=　1198.4(5)　Å3,　Z　=　1,　Dc　=　3.325　g/cm3,　F(000)　=　1048.0,　μ(MoKα)　=　17.951　mm　-1,　the　final　R　=　0.0412　and　wR　=　0.0993　for　3375　observed　reflections　with　I　>　2σ(I).　The　title　compound　consists　of　[Zn(C　8H23N5)]2+　cations　and　anionic　chains　[Pb3I10]n4n-,　which　are　combined　with　each　other　via　electrostatic　attractive　forces　and　N-H⋯I　hydrogen　bonds.

Keyword：

Chain-like structure; Crystal structure; Iodoplumbate; Polymeric complex

Community：

[ 1 ] [Ye, R.-B.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China
[ 2 ] [Huang, C.-C.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Zhang, H.-H.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China
[ 4 ] [Li, H.-H.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China
[ 5 ] [Yang, Q.-Y.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China
[ 6 ] [Sun, R.-Q.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China

Reprint 's Address：

黄长沧
[Huang, C.-C.]Department of Chemistry, Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

cchuang@fzu.edu.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2005

Issue： 6

Volume： 24

Page： 679-683

0 . 6 6 9

JCR@2005

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 2

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