A Bicapped α-Keggin unit-supported transition metal complex: Hydrothermal synthesis and characterization of [Cu(en)2(H 2O)]2[Cu(en)2]0.5[Mo 8V7O42{Cu(en)2}] - Details

author：

Zeng, Q.-X. (Zeng, Q.-X..) ^[1] | Xu, J.-Q. (Xu, J.-Q..) ^[2] | Song, Y.-J. (Song, Y.-J..) ^[3] | Cui, X.-B. (Cui, X.-B..) ^[4] | Shi, Z. (Shi, Z..) ^[5]

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Abstract：

A　new　metal-oxo　cluster　supported　transition　metal　complex,　[Cu(en)　2(H2O)]2[Cu(en)2]　0.5[MoVI8VIV6V　vO42{Cu(en)2}],　has　been　synthesized　under　hydrothermal　conditions.　Its　structure　was　determined　by　single-crystal　X-ray　diffraction.　The　compound　crystallizes　in　the　triclinic　system,　space　group　P1　(No.　2),　a　=　12.245(5),　b　=　12.669(5),　c　=　20.949(8)　Å,　α　=　77.120(13),　β　=　78.107(17),　γ　=　65.560(14)°,　V　=　2860(2)　Å3,　Z　=　2.　The　metal-oxo　cluster　contains　a　novel　bicapped　a-Keggin　structure　unit　and　a　[Cu(en)2]2+　unit　covalently　bonded　to　the　[Mo8V7O42]7-　cluster.　©　2005　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA.

Keyword：

Bicapped α-Keggin structure; Crystal elucidation; Hydrothermal synthesis; Metal-oxo cluster

Community：

[ 1 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian, China
[ 2 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China
[ 3 ] [Xu, J.-Q.]Department of Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, China
[ 4 ] [Song, Y.-J.]Department of Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, China
[ 5 ] [Cui, X.-B.]Department of Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, China
[ 6 ] [Shi, Z.]Department of Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, China

Reprint 's Address：

[Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China

Email：

zengqx2004@yahoo.com.cn

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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2005

Issue： 8

Volume： 631

Page： 1528-1531

1 . 2 0 2

JCR@2005

1 . 1 0 0

JCR@2023

JCR Journal Grade：3

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