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author:

Xia, Jing (Xia, Jing.) [1] | Gao, Yanxin (Gao, Yanxin.) [2] (Scholars:高琰昕) | Yu, Gang (Yu, Gang.) [3]

Indexed by:

EI SCIE

Abstract:

The adsorptive removal of tetracycline (TC) was studied with three types of zirconium-based metal-organic frameworks (Zr-MOFs), UiO-66, NU-1000 and MOF-525. The adsorption kinetics best fitted with the pseudo-second-order kinetic model and the adsorption equilibrium was rapidly reached within 40 min on UiO-66 and NU-1000, and 120 min on MOF-525. The adsorption isotherms best fitted with Sips model, and the maximum Sips adsorption capacities of TC on UiO-66, NU-1000 and MOF-525 were 145 mg.g(-1), 356 mg.g(-1) and 807 mg.g(-1) respectively, which were much higher than common adsorbents. The X-ray photoelectron spectra measurements and the influence of pH suggested that the pi-pi interaction played a crucial role during the adsorption. Pore characteristics and topology of MOFs showed great effect on adsorption performance. The cages whose size match well with TC helped MOF-525 to get highest adsorption amount per surface area among MOFs we studied. The proper topology of NU-1000 contributed to its high adsorption rate. River water was also used to confirm the excellent adsorptive performance of these three Zr-MOFs in practical application. These results might aid us to comprehend the adsorption of TC on Zr-MOFs and expand the application of Zr-MOFs in water treatment for removal of emerging contaminants. (C) 2021 Published by Elsevier Inc.

Keyword:

Adsorption Isotherm Kinetic Mechanism Metal-organic framework (MOF) Pore size Tetracycline Topology

Community:

  • [ 1 ] [Xia, Jing]Tsinghua Univ, Beijing Key Lab Emerging Organ Contaminants Contr, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China
  • [ 2 ] [Yu, Gang]Tsinghua Univ, Beijing Key Lab Emerging Organ Contaminants Contr, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China
  • [ 3 ] [Gao, Yanxin]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Yu, Gang]Tsinghua Univ, Beijing Key Lab Emerging Organ Contaminants Contr, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China

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Source :

JOURNAL OF COLLOID AND INTERFACE SCIENCE

ISSN: 0021-9797

Year: 2021

Volume: 590

Page: 495-505

9 . 9 6 5

JCR@2021

9 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 149

SCOPUS Cited Count: 158

ESI Highly Cited Papers on the List: 16 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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