• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Chen, Qiulin (Chen, Qiulin.) [1] | Liu, Ben (Liu, Ben.) [2] | Zhang, Li (Zhang, Li.) [3] | Xie, Qingshui (Xie, Qingshui.) [4] | Zhang, Yinggan (Zhang, Yinggan.) [5] | Lin, Jie (Lin, Jie.) [6] | Qu, Baihua (Qu, Baihua.) [7] | Wang, Laisen (Wang, Laisen.) [8] | Sa, Baisheng (Sa, Baisheng.) [9] (Scholars:萨百晟) | Peng, Dong-Liang (Peng, Dong-Liang.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Sodium is regarded as a promising electrode material in the post lithium ion battery era due to its high theoretical specific capacity of 1166 mAh g(-1), low electrochemical potential (-2.71 V vs standard hydrogen electrode), low cost and high natural abundance. However, similar to lithium metal anode, sodium metal anode also shares the problems of uncontrollable dendrites growth, formation of unstable solid electrolyte interface and large volume change during repeated plating/stripping. Herein, a porous sodiophilic zinc metal framework modified with SnO2 surface layer is introduced on copper substrate and used as 3D current collector for sodium metal batteries in order to realize even deposition of Na, moderate the volume change and construct a stable solid electrolyte interface layer simultaneously. Theoretical calculations based on density functional theory are used to interpret the deposition behavior of the metallic Na on different current collectors. The electrochemical performance results show that the Cu/Zn/SnO2@Na symmetric cell can deliver an extremely low nucleation overpotential (0 mV), outstanding long-term rate performance over 1000 h and also can be cycled for around 700 h even at a high current density of 5 mA cm(-2) for total capacity of 5 mAh cm(-2). Cu/Zn/SnO2@Na//Na3V2(PO4)(3) full cell is also constructed to display the feasible application of the designed Cu/Zn/SnO2 porous current collector in advanced sodium metal anode.

Keyword:

Low nucleation energy Na2O surface layer Porous Zn scaffold Sodium affinity Sodium metal anode

Community:

  • [ 1 ] [Chen, Qiulin]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 2 ] [Zhang, Li]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 3 ] [Xie, Qingshui]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 4 ] [Zhang, Yinggan]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 5 ] [Lin, Jie]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 6 ] [Wang, Laisen]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 7 ] [Peng, Dong-Liang]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China
  • [ 8 ] [Liu, Ben]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 9 ] [Qu, Baihua]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 10 ] [Sa, Baisheng]Fuzhou Univ, Coll Mat Sci & Engn, Multiscale Computat Mat Facil, Fuzhou 350100, Peoples R China

Reprint 's Address:

  • [Xie, Qingshui]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China;;[Zhang, Yinggan]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China;;[Peng, Dong-Liang]Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, State Key Lab Phys Chem Solid Surfaces, Fujian Key Lab Mat Genome,Coll Mat, Xiamen 361005, Peoples R China

Show more details

Related Keywords:

Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 404

1 6 . 7 4 4

JCR@2021

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 29

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:217/10031653
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1