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author:

Chen, Jinyi (Chen, Jinyi.) [1] | Wang, Hongxing (Wang, Hongxing.) [2]

Indexed by:

EI SCIE

Abstract:

Density and viscosity data of pure 3-chloro-4-fluoronitrobenzene and 3-chloro-2-fluoronitrobenzene were obtained in temperature range from 318.15 K to 348.15 K at the local atmospheric pressure of 99.7 kPa. The value of corresponding saturated vapour pressure of two isomers were determined in the temperature range of 409 K to 517 K. The relationship between temperature and density can be well correlated by the linear equation. The viscosity data was well described by the Litovitz, Ghatee, VFT, and Andrade equations, and the calculated value by the VFT equation is consistent with the measured data. Both the Antoine and Riedel equations can accurately describe the relationship between saturated vapour pressure and temperature of 3-chloro-4-fluoronitrobenzene and 3-chloro-2-fluoronitrobenzene, which can meet the requirements for chemical design. In addition, the thermal expansion coefficient was determined based on the density data, and the molar vaporisation enthalpy of two isomers was evaluated using the Clausius-Clapeyron equation. (C) 2020 Elsevier Ltd.

Keyword:

3-chloro-2-fluoron trobenzene 3-chloro-4-fluoronitrobenzene Density Vapour pressure Viscosity

Community:

  • [ 1 ] [Chen, Jinyi]Fujian Polytech Normal Univ, Sch Ocean Sci & Biochem Engn, Fuzhou 350300, Fujian, Peoples R China
  • [ 2 ] [Chen, Jinyi]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Wang, Hongxing]Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, Tianjin 300222, Peoples R China

Reprint 's Address:

  • [Wang, Hongxing]Tianjin Univ Sci & Technol, Coll Chem Engn & Mat Sci, Tianjin 300222, Peoples R China

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Source :

JOURNAL OF CHEMICAL THERMODYNAMICS

ISSN: 0021-9614

Year: 2021

Volume: 154

3 . 2 6 9

JCR@2021

2 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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