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author:

Zhang, Weibin (Zhang, Weibin.) [1] | Li, Yongwang (Li, Yongwang.) [2] | Ye, ShanShan (Ye, ShanShan.) [3] | Zhou, Jiangcong (Zhou, Jiangcong.) [4] | Wu, Dewu (Wu, Dewu.) [5] | Shi, Chen (Shi, Chen.) [6] | Chen, Mengting (Chen, Mengting.) [7] | Ding, Jianyan (Ding, Jianyan.) [8] | Wu, Quansheng (Wu, Quansheng.) [9]

Indexed by:

EI SCIE

Abstract:

Cyan phosphors have attracted considerable attention in recent years as an indispensable component for realizing full-spectrum lighting. In this study, a novel nitride-based cyan-emitting phosphor Ca2BN2Cl:Eu2+ was successfully prepared. Its crystal structure refined by the Rietveld refinement reveals that Ca2BN2Cl is formed by a tight host lattice and the edge-sharing Ca(N,Cl)(4) tetrahedrons along with multiple crystallographic Ca sites for Eu2+ ions to occupy, which corresponds to its broad emission band. Under the near ultraviolet (NUV) light excitation, Ca2BN2Cl:Eu2+ emits a broad-band cyan light and its full width at half-maximum (FWHM) can reach 121 nm, which effectively compensates the "cyan cavity". The time-resolved photoluminescence (TRPL) spectra of Ca2BN2Cl:Eu2+ were investigated to expose the energy transfer between the multiple luminescent centers. Furthermore, the temperature-dependent spectra of Ca2BN2Cl:Eu2+ were measured to evaluate its thermal stability. All of the discussion and results reveal that Ca2BN2Cl:Eu2+ is a promising cyan phosphor for use in white light-emitting diodes to realize full-spectrum lighting.

Keyword:

Community:

  • [ 1 ] [Zhang, Weibin]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 2 ] [Li, Yongwang]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 3 ] [Zhou, Jiangcong]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 4 ] [Wu, Dewu]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 5 ] [Shi, Chen]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 6 ] [Chen, Mengting]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 7 ] [Ding, Jianyan]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 8 ] [Wu, Quansheng]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China
  • [ 9 ] [Zhang, Weibin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Li, Yongwang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Shi, Chen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Chen, Mengting]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 13 ] [Ye, ShanShan]Longyan Univ, Sch Math & Informat Engn, Longyan 364000, Fujian, Peoples R China

Reprint 's Address:

  • [Ding, Jianyan]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China;;[Wu, Quansheng]Longyan Univ, Coll Chem & Mat Sci, Longyan 361000, Fujian, Peoples R China

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Source :

DALTON TRANSACTIONS

ISSN: 1477-9226

Year: 2021

Issue: 30

Volume: 50

Page: 10446-10454

4 . 5 6 9

JCR@2021

3 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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