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author:

Guo, Hui (Guo, Hui.) [1] | Kuang, Ge (Kuang, Ge.) [2] (Scholars:旷戈) | Li, Huan (Li, Huan.) [3] | Pei, Wen-tao (Pei, Wen-tao.) [4] | Wang, Hai-dong (Wang, Hai-dong.) [5]

Indexed by:

EI SCIE CSCD

Abstract:

An acidic mixture of sulfuric and fluosilicic acid (H2SO4+H2SiF6) was employed as lixiviant to enhance leaching of lithium from lepidolite. The H2SiF6 was obtained as a byproduct of anhydrous hydrofluoric acid production, aiming to provide HF molecules. It was found that the HF molecules were the main reaction component and played a key role in strengthening the dissolution of lepidolite. Different factors, including mass ratio of ore/H2SO4+H2SiF6, concentrations of H2SO4 and H2SiF6, leaching temperatures (40-80 degrees C) and time (15-75 min), were investigated. Moreover, an efficient tubular reactor was employed to improve this acid leaching system. Under the optimal conditions (ore/H2SO4+H2SiF6 mass ratio of 1:0.8:1.6, 80 wt.% H2SO4, 15 wt.% H2SiF6, 80 degrees C, 15 min), 97.9% of Li, 96.4% of K, 97.6% of Rb, 96.7% of Cs and 81.4% of Al (mass fraction) were leached. Additionally, a two-step thermal process was proposed to remove fluorine of leaching slurry. This acid treatment using an acidic mixture of H2SO4 and H2SiF6 in a continuous tubular reactor shows potential as an alternative process to extract lithium from lepidolite.

Keyword:

continuous tubular reactor fluorine chemical method fluosilicic acid lepidolite lithium extraction

Community:

  • [ 1 ] [Guo, Hui]Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Peoples R China
  • [ 2 ] [Guo, Hui]Fuzhou Univ, Coll Chem Engn, Inst Chem Technol, Fuzhou 350108, Peoples R China
  • [ 3 ] [Kuang, Ge]Fuzhou Univ, Coll Chem Engn, Inst Chem Technol, Fuzhou 350108, Peoples R China
  • [ 4 ] [Li, Huan]Fuzhou Univ, Coll Chem Engn, Inst Chem Technol, Fuzhou 350108, Peoples R China
  • [ 5 ] [Pei, Wen-tao]Fuzhou Univ, Coll Chem Engn, Inst Chem Technol, Fuzhou 350108, Peoples R China
  • [ 6 ] [Guo, Hui]Cent South Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China
  • [ 7 ] [Wang, Hai-dong]Cent South Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China
  • [ 8 ] [Li, Huan]Curtin Univ, Western Australian Sch Mines Minerals Energy & Ch, Perth, WA 6102, Australia

Reprint 's Address:

  • 旷戈

    [Kuang, Ge]Fuzhou Univ, Coll Chem Engn, Inst Chem Technol, Fuzhou 350108, Peoples R China;;[Wang, Hai-dong]Cent South Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Peoples R China

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Source :

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA

ISSN: 1003-6326

CN: 43-1239/TG

Year: 2021

Issue: 7

Volume: 31

Page: 2165-2173

3 . 7 5 2

JCR@2021

4 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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