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author:

Wang, Ruirui (Wang, Ruirui.) [1] | Yang, Pengju (Yang, Pengju.) [2] | Wang, Sibo (Wang, Sibo.) [3] (Scholars:汪思波) | Wang, Xinchen (Wang, Xinchen.) [4] (Scholars:王心晨)

Indexed by:

EI SCIE

Abstract:

Polymeric carbon nitrides (PCNs) are attractive candidates for diverse photoredox catalysis, but the CO2 reduction activity of pristine PCNs is unsatisfactory, mainly due to the bulky structure and insufficient optical harvesting. In this work, a facile and efficient strategy coupling copolymerization and stream reforming is developed to exfoliate the bulky PCNs into PCN nanosheets (named PCN-T-NSs). The ameliorated morphological and electronic structures of PCN-T-NSs enable the exposure of abundant catalytically-active sites, accelerated separation of photogenerated charge carriers, and strengthened photoabsorption in the visible region. Consequently, the optimized PCN-T-NS photocatalyst shows a greatly enhanced CO2 reduction activity, with a remarkable CO-releasing rate of 43 mu mol h(-1), which is about 40 times greater than that of pristine PCN. Besides, a high apparent quantum efficiency (AQE) of 4.2% is realized by the PCN-T-NS catalyst under 420 nm photoirradiation with TEOA as a sacrificial reagent and Co(bpy)(3)(2+) as a cocatalyst. Moreover, the integrated copolymerization and stream reforming strategy is extendable to the assembly of several other carbon nitride nanosheets with enhanced performance for CO2 photoreduction by employing the typical comonomers. This work may bring some fresh vitality for constructing well-tailored carbon nitride polymers with functions for sustainable solar-to-chemical energy conversion.

Keyword:

Community:

  • [ 1 ] [Wang, Ruirui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 2 ] [Wang, Sibo]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 4 ] [Yang, Pengju]Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China

Reprint 's Address:

  • 王心晨

    [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

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Source :

CATALYSIS SCIENCE & TECHNOLOGY

ISSN: 2044-4753

Year: 2021

Issue: 7

Volume: 11

Page: 2570-2576

6 . 1 7 7

JCR@2021

4 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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