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author:

Cui, Qingyan (Cui, Qingyan.) [1] (Scholars:崔勍焱) | Ma, Xiaoliang (Ma, Xiaoliang.) [2] | Nakano, Koji (Nakano, Koji.) [3] | Nakabayashi, Koji (Nakabayashi, Koji.) [4] | Miyawaki, Jin (Miyawaki, Jin.) [5] | Al-Mutairi, Adel (Al-Mutairi, Adel.) [6] | Marafi, Abdulazeem M. J. (Marafi, Abdulazeem M. J..) [7] | Al-Otaibi, Ahmed M. (Al-Otaibi, Ahmed M..) [8] | Yoon, Seong-Ho (Yoon, Seong-Ho.) [9] | Mochida, Isao (Mochida, Isao.) [10]

Indexed by:

EI SCIE

Abstract:

In order to clarify the effect of blending heavy atmospheric residues (AR) and light AR on reactivities for hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodevanadium (HDV), hydrodenickel (HDNi), hydrodeasphaltenes (HDAsp) and hydrodeconradson-carbon-residue (HDCCR) in hydrotreating process, hydrotreating of the blends from two ARs at different ratios was conducted in a fixed-bed unit at 370 degrees C under a H-2 pressure of 13.5 MPa over a set of commercial HDM and HDS catalysts. The compositions and properties of the two ARs and their blends as well as their hydrotreated products were analyzed and compared in detail. A positive synergistic effect of the blending was found for HDS, HDN and HDCCR, while a negative synergistic effect of the blending was observed for HDAsp, HDV and HDNi. A synergistic effect index (eta(i),s) was proposed to describe quantitatively the extent of the blending synergistic effect. The observed synergistic effects can be attributed to change of the aromatics-to-saturates ratio in the blends. In addition, composition and property of the hydrotreated products from the blending feedstocks with different blending ratios were well estimated on the basis of the developed models with an average relative deviation less than 1.5 %.

Keyword:

Atmospheric residue Blending Hydrotreatment Synergy

Community:

  • [ 1 ] [Cui, Qingyan]Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
  • [ 2 ] [Nakabayashi, Koji]Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
  • [ 3 ] [Miyawaki, Jin]Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
  • [ 4 ] [Yoon, Seong-Ho]Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan
  • [ 5 ] [Ma, Xiaoliang]Kuwait Inst Sci Res, Petr Res Ctr, Safat 13109, Kuwait
  • [ 6 ] [Al-Mutairi, Adel]Kuwait Inst Sci Res, Petr Res Ctr, Safat 13109, Kuwait
  • [ 7 ] [Marafi, Abdulazeem M. J.]Kuwait Inst Sci Res, Petr Res Ctr, Safat 13109, Kuwait
  • [ 8 ] [Al-Otaibi, Ahmed M.]Kuwait Inst Sci Res, Petr Res Ctr, Safat 13109, Kuwait
  • [ 9 ] [Nakano, Koji]JGC Catalysts & Chem Ltd, Fukuoka 2120013, Japan
  • [ 10 ] [Mochida, Isao]Kyushu Environm Evaluat Assoc, Fukuoka 8130004, Japan
  • [ 11 ] [Cui, Qingyan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Ma, Xiaoliang]Kuwait Inst Sci Res, Petr Res Ctr, Safat 13109, Kuwait;;[Mochida, Isao]Kyushu Environm Evaluat Assoc, Fukuoka 8130004, Japan

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Source :

FUEL

ISSN: 0016-2361

Year: 2021

Volume: 293

8 . 0 3 5

JCR@2021

6 . 7 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Online/Total:263/10000184
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