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author:

Xing, Fangshu (Xing, Fangshu.) [1] | Cheng, Chuchu (Cheng, Chuchu.) [2] | Zhang, Jingwen (Zhang, Jingwen.) [3] | Liu, Qiuwen (Liu, Qiuwen.) [4] | Chen, Cheng (Chen, Cheng.) [5] | Huang, Caijin (Huang, Caijin.) [6] (Scholars:黄彩进)

Indexed by:

EI SCIE

Abstract:

A Z-scheme system is ideal for photocatalysis hydrogen evolution due to spatially separating photogenerated electron-hole pairs and strong redox ability. However, the construction of such a system to achieve rapid charge transfer is still a big challenge. Hierarchical functional nanomaterials with controllable morphology, dimensionality, and electronic property can open more possibilities for designing active Z-scheme photocatalysts. Herein, we construct hierarchical direct Z-scheme composites of epitaxial ultrathin ZnIn2S4 nanosheets on HxMoO3 nanobelts, which exhibits 10.5 times higher H-2-production activity (5.9 mmol.g(-1).h(-1)) than pristine ZnIn2S4 with visible light. High conductivity and tunable charge transfer efficiency of HxMoO3 component resulting from hydrogen intercalation are favourable to the effective transport of charge carriers. Moreover, hierarchical architecture composed of 2D nanosheets increases intimate interface for effective separation of electron-hole pairs and exposes more reactive sites. The study provides a new sight in designing hierarchical direct Z-scheme photocatalyst for solar fuel generation.

Keyword:

Hierarchical structure Hydrogen evolution Molybdenum bronze Photocatalysis Z-scheme

Community:

  • [ 1 ] [Xing, Fangshu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 2 ] [Cheng, Chuchu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang, Jingwen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 4 ] [Liu, Qiuwen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 5 ] [Huang, Caijin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 6 ] [Liu, Qiuwen]Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Sch Chem & Chem Engn, Frontiers Sci Ctr Transformat Mol, Shanghai 200240, Peoples R China
  • [ 7 ] [Chen, Cheng]Anhui Agr Univ, Sch Resources & Environm, Anhui Prov Key Lab Farmland Ecol Conservat & Poll, Hefei 230036, Peoples R China

Reprint 's Address:

  • 黄彩进

    [Huang, Caijin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

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Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2021

Volume: 285

2 4 . 3 1 9

JCR@2021

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 102

SCOPUS Cited Count: 101

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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