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author:

Wang, Jinyun (Wang, Jinyun.) [1] | Chen, Shubin (Chen, Shubin.) [2] | Lin, Tengfei (Lin, Tengfei.) [3] (Scholars:林腾飞) | Ke, Jinhuang (Ke, Jinhuang.) [4] | Chen, Tianxiang (Chen, Tianxiang.) [5] | Wu, Xiao (Wu, Xiao.) [6] (Scholars:吴啸) | Lin, Cong (Lin, Cong.) [7] (Scholars:林枞)

Indexed by:

Scopus SCIE

Abstract:

Vitrimers, as intriguing polymers, possess exchangeable links in the crosslinking networks, endowing them with the abilities of recycling and reprocessing. However, most of vitrimers are generally fabricated via complex synthesis and polymerization processes. Toxic and unstable exogenous catalysts are inevitably applied to activate the exchange reaction to rearrange the crosslinking networks. These drawbacks limit the widespread applications of vitrimers. Moreover, most reported vitrimers could only partially maintain or severely deteriorate their mechanical properties after recycling. Herein, to solve the above-mentioned problems, for the first time, a catalyst-free and recycle-reinforcing elastomer vitrimer is revealed. By the reactive blending of commercially available epoxidized natural rubber and carboxylated nitrile rubber, the elastomer vitrimer associated with exchangeable beta-hydroxyl ester bonds was obtained. Strikingly, the vitrimer exhibits an exceptional recycle-reinforcing property. This work provides a feasible method to fabricate elastomer vitrimers, which promotes the recycling of crosslinking commercial available elastomers.

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Community:

  • [ 1 ] [Wang, Jinyun]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Shubin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Lin, Tengfei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Ke, Jinhuang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Chen, Tianxiang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Lin, Cong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 林腾飞

    [Lin, Tengfei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

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RSC ADVANCES

ISSN: 2046-2069

Year: 2020

Issue: 64

Volume: 10

Page: 39271-39276

3 . 3 6 1

JCR@2020

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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