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author:

Wu, Hefeng (Wu, Hefeng.) [1] | Gan, Yanmei (Gan, Yanmei.) [2] | Yao, Qianqian (Yao, Qianqian.) [3] | Wang, Luyuan Paul (Wang, Luyuan Paul.) [4] | Wang, Chaoying (Wang, Chaoying.) [5] | Zhang, Qixin (Zhang, Qixin.) [6] | Hou, Kun (Hou, Kun.) [7] | Zhao, Yi (Zhao, Yi.) [8] | Guan, Lunhui (Guan, Lunhui.) [9]

Indexed by:

SCIE

Abstract:

Transition metal oxides with high theoretical capacities are widely investigated as potential anodes for alkali-metal ion batteries. However, the intrinsic conductivity deficiency and large volume changes during cycles result in poor cycling stability and low rate capabilities. Graphene has been widely used to support metal oxide for enhanced performance, but the cycling life is limited by the aggregation/collapse of active materials on graphene surface. Herein, we significantly improve the battery performance of graphene-metal oxide composite via pore engineering and surface protection. In this architecture, the mesoporous NiFe2O4 is designed for fast ion diffusion and volume accommodation, and the outer graphene protection can further enhance the electrical conductivity and prevent the aggregation during cycle. Thus, as-prepared G@p-NiFe2O4@G composite for lithium storage delivers high capacity (1244 mA h g(-1) after 300 cycles at 0.2 A g(-1)), excellent rate performance (563 mA h g(-1) at 4 A g(-1)), and outstanding cycling life up to 1200 cycles at 1.5 A g(-1). For sodium storage, it also displays good cycling stability and superior rate performance. Moreover, the effects of various microstructures on the battery performance, the reaction kinetics of various electrodes, and the reaction mechanism of NiFe2O4 have been systematically investigated in this work.

Keyword:

graphene coating lithium-ion batteries NiFe2O4 porous structure sodium-ion batteries

Community:

  • [ 1 ] [Wu, Hefeng]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Gan, Yanmei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Wu, Hefeng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 4 ] [Gan, Yanmei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 5 ] [Yao, Qianqian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 6 ] [Wang, Chaoying]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zhang, Qixin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 8 ] [Hou, Kun]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 9 ] [Zhao, Yi]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 10 ] [Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China
  • [ 11 ] [Wang, Luyuan Paul]Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore

Reprint 's Address:

  • [Zhao, Yi]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China;;[Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350108, Peoples R China

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Source :

NANOTECHNOLOGY

ISSN: 0957-4484

Year: 2021

Issue: 10

Volume: 32

3 . 9 5 3

JCR@2021

2 . 9 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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