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author:

Gan, Xianqian (Gan, Xianqian.) [1] | Chen, Lu (Chen, Lu.) [2] | Chen, Xiaohui (Chen, Xiaohui.) [3] (Scholars:陈晓晖) | Pan, Shouquan (Pan, Shouquan.) [4] | Pan, Hongkun (Pan, Hongkun.) [5]

Indexed by:

EI SCIE

Abstract:

Corncob, an agricultural bio-waste, was used as adsorbent to remove organic and inorganic contaminants in waste lubricating oil (WLO) from diesel engine. To improve its adsorption capacity, corncob was modified with mixed solution of nitric acid, Hexadecyl trimethyl ammonium bromide and ethanol. Characterization results showed the crystallinity index of corncob enhanced 12%, which would be ascribed to the disruption of the dense lignin-carbohydrates structure in lignocellulose biomass by modification. The surface of modified corncob became smoother and porous. The adsorption results showed modified corncob had better removal rates to contaminants than raw corncob. For WLO with 80,000 km mileage, the removal rates to Fe, Al, Cu were enhanced from 19%, 6.4%, 48-27%, 27%, 53%, while that for oxide, sulphate, aromates, soot and insoluble resins were enhanced 1.7, 1.2, 3.0, 1.7 and 1.7 times. The reduction rate of total acid number to WLO with 40,000, 60,000, 80,000 km were enhanced 16%, 9%, 12% by modified corncob, respectively. The optimal adsorption condition was explored as adsorbing 60 min at 90 degrees C with 2% adsorbent. Corncob, with the advantages of low cost, good biodegradability and high adsorption capacity, could be used as alternative to conventional adsorbent for WLO.

Keyword:

Adsorption Modified corncob Organic contaminant Total acid number Wear metals

Community:

  • [ 1 ] [Gan, Xianqian]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Chen, Lu]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Chen, Xiaohui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Gan, Xianqian]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Chen, Lu]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Chen, Xiaohui]Fuzhou Univ, Sch Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 7 ] [Pan, Shouquan]Fuzhou Savon Environm Technol Co Ltd, Fuzhou 350026, Peoples R China
  • [ 8 ] [Pan, Hongkun]Fuzhou Savon Environm Technol Co Ltd, Fuzhou 350026, Peoples R China

Reprint 's Address:

  • 陈晓晖

    [Chen, Xiaohui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Sch Chem Engn, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF HAZARDOUS MATERIALS

ISSN: 0304-3894

Year: 2021

Volume: 414

1 4 . 2 2 4

JCR@2021

1 2 . 2 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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