Volume　changechange　during　the　insertion/extractio　of　Li+　in　electrode　materials　is　in　important　issue　to　affect　the　safety　and　stability　of　Li-ion　batteries.　Here,　we　prepare　a　near-zero　volume　change　material　of　COF　derived　mesh-liked　carbon/TiO2　(MC/TiO2)　composite　by　using　a　layered　TiO2　as　a　template,　and　a　two-dimensional　COF　material　is　insert　into　the　interlayers　by　the　Schiff　base　polymerization　between　melamine　and　terephthalaldehyde,　followed　by　carbonization　at　500　degrees　C　to　convert　COF　to　mesh-liked　carbon　nanosheets.　Due　to　the　introduction　of　mesh-liked　carbon　nanosheets,　the　interlayer　conductivity　of　TiO2　is　improved,　and　the　nanocavities　in　mesh-liked　carbon　nanosheets　provide　additional　chambers　for　the　insertion/extraction　Li-ions　without　any　change　of　the　interlayer　distance.　The　MC/TiO2　shows　a　specific　capacity　of　472.7　mAh/g　at　a　current　density　of　0.1　A/g,　and　good　specific　capacity　retention　of　65%　remains　after　1000　cycles　at　a　current　of　1　A/g.