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author:

Wang, Peng (Wang, Peng.) [1] | Lin, Jinfeng (Lin, Jinfeng.) [2] | Wu, Xiao (Wu, Xiao.) [3] (Scholars:吴啸) | Zhao, Chunlin (Zhao, Chunlin.) [4] (Scholars:赵纯林) | Gao, Min (Gao, Min.) [5] (Scholars:高旻) | Lin, Cong (Lin, Cong.) [6] (Scholars:林枞) | Zhang, Qiwei (Zhang, Qiwei.) [7]

Indexed by:

EI SCIE

Abstract:

Most photochromic ceramics can back up post-irradiation to achieve color state transition. Unfortunately, color recovery usually requires exposure of material to external physical fields (such as light and heat), which severely limits the application as a convenient energy building material such as smart windows. Here, we report a kind of sodium niobate translucent ceramics whose photochromic effect can be completely self-recoverable without any external physical field stimulation. Based on the analysis of time-response transmittance, up-conversion emission spectra and thermoluminescence spectra, the behavior of carrier migration and trap capture/release in the process of self-recovery photochromic reaction has been proposed. It is believed that the emergence of intermediate trap level is an important factor to produce this spontaneous behavior. Moreover, by controlling the amount of rare earth doping and designing two types of materials with different carrier behaviors, Sm/Ercodoped NaNbO3 ceramics are regarded as an appropriate candidate for tracing the time of light irradiation and intelligent regulation of smart building materials. This work can promote the fundamental understanding and practical applications of self-recoverable photochromic bulk materials.

Keyword:

Photochromic Rare earth doping Sodium niobate Transparent ceramics

Community:

  • [ 1 ] [Wang, Peng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Gao, Min]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Cong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Lin, Jinfeng]Tongji Univ, Sch Mat Sci & Engn, Shanghai 201804, Peoples R China
  • [ 7 ] [Zhang, Qiwei]Inner Mongolia Univ Sci & Technol, Sch Met & Mat, Baotou 014010, Peoples R China

Reprint 's Address:

  • 吴啸

    [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

CERAMICS INTERNATIONAL

ISSN: 0272-8842

Year: 2021

Issue: 22

Volume: 47

Page: 31702-31712

5 . 5 3 2

JCR@2021

5 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Online/Total:356/10036000
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