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author:

Yang, Miao (Yang, Miao.) [1] | Qiu, Fenglei (Qiu, Fenglei.) [2] | M. El-Sayed, El-Sayed (M. El-Sayed, El-Sayed.) [3] | Wang, Wenjing (Wang, Wenjing.) [4] | Du, Shunfu (Du, Shunfu.) [5] | Su, Kongzhao (Su, Kongzhao.) [6] | Yuan, Daqiang (Yuan, Daqiang.) [7]

Indexed by:

EI SCIE

Abstract:

Although porous organic cages (POCs), particularly imine-linked (C=N) ones, have advanced significantly over the last few decades, the reversible nature of imine linkages makes them prone to hydrolysis and structural collapse, severely limiting their applications under moist or water conditions. Herein, seven water-stable hydrazone-linked (C=N-N) POCs are prepared through a simple coupling of the same supramolecular tetraformylresorcin[4]arene cavitand with different dihydrazide linkers. Their structures are all determined by single-crystal X-ray crystallography, demonstrating rich structural diversity from the [2 + 4] lantern, [3 + 6] triangular prism, and unprecedented [4 + 8] square prism to the extra-large [6 + 12] octahedron. In addition, they respectively exhibit tunable window diameters and cavity volumes ranging from about 5.4 to 11.1 nm and 580 to 6800 angstrom 3. Moreover, their application in the water environment for pollutant removal was explored, indicating that they can effectively eliminate various types of contaminants from water, including radionuclide waste, toxic heavy metal ions, and organic micropollutants. This work demonstrates a convenient method for rationally constructing versatile robust POCs and presents their great application potentialities in water medium.

Keyword:

Community:

  • [ 1 ] [Yang, Miao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] [Qiu, Fenglei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [M. El-Sayed, El-Sayed]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Wang, Wenjing]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Du, Shunfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 6 ] [Su, Kongzhao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 7 ] [Yuan, Daqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 8 ] [Yang, Miao]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
  • [ 9 ] [M. El-Sayed, El-Sayed]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 10 ] [Wang, Wenjing]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 11 ] [Su, Kongzhao]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 12 ] [Yuan, Daqiang]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 13 ] [Qiu, Fenglei]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 14 ] [Du, Shunfu]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 15 ] [M. El-Sayed, El-Sayed]Egyptian Petr Res Inst, Refining Dept, Chem Refining Lab, Nasr City 11727, Egypt

Reprint 's Address:

  • [Su, Kongzhao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Yuan, Daqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Su, Kongzhao]Univ Chinese Acad Sci, Beijing 100049, Peoples R China;;[Yuan, Daqiang]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

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Source :

CHEMICAL SCIENCE

ISSN: 2041-6520

Year: 2021

Issue: 40

Volume: 12

9 . 9 6 9

JCR@2021

7 . 6 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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