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author:

Alenad, Asma M. (Alenad, Asma M..) [1] | Taha, T. A. (Taha, T. A..) [2] | Amin, Mohammed A. (Amin, Mohammed A..) [3] | Irfan, Ahmad (Irfan, Ahmad.) [4] | Oliva, J. (Oliva, J..) [5] | Al-Hadeethi, Yas (Al-Hadeethi, Yas.) [6] | Palamanit, Arkom (Palamanit, Arkom.) [7] | Khan, Muhammad (Khan, Muhammad.) [8] | Hayat, Asif (Hayat, Asif.) [9] | Mane, Sunil Kumar Baburao (Mane, Sunil Kumar Baburao.) [10] | Sohail, Muhammad (Sohail, Muhammad.) [11]

Indexed by:

SCIE

Abstract:

An ideal solution to water or pollutant contamination and energy problem is to advance photocatalysts that are highly effective for both reducing contaminants and cleaning water. In this regard, carbon nitride (CN) has strong stability with prominent band structure and can be used to produce hydrogen through water splitting due to an easier fabrication process. Uric acid (UA) was integrated as a conjugated monomer in the urea based CN system using the molecular doping (copolymerization) process. The photocatalysis of water reduction (HER) by using a new growth technique of minimally priced effective monomer UA inside CN, which also optimized the photodegradation of Rhodamine B dye (RhB) under light illumination (lambda = 420 nm). By increasing light transmittance, speeding up photogenerated electrons and holes, and changing the physicochemical properties of CN, modified samples dramatically improve photocatalytic efficiency. The ideal samples CNU-UA10.0 showed a substantial increase in photocatalytic activity, with an HER 690.01 mu mol/h higher than CNU (82.89 mu mol/h), based on the implications of different configurations on the reaction mechanism. Moreover, an extraordinary apparent quantum yield (AQY) of about 57.43% at 420 nm has been observed for CNU-UA10.0. Under the same conditions and illuminations, H2 performance versus RhB dye degradation was compared. CNU-UA, on the other hand, had a three-fold higher pseudo-order kinetic constant for photodegradation of RhB than CN. The results demonstrate a major step toward in the direction of custom-designed photocatalysts with efficient water reduction and pollutants degradation capability for future demand.

Keyword:

Carbon nitride (CN) RhB degradation Uric acid (UA) Water reduction(H2)

Community:

  • [ 1 ] [Alenad, Asma M.]Jouf Univ, Coll Sci, Chem Dept, POB 2014, Sakaka, Saudi Arabia
  • [ 2 ] [Taha, T. A.]Jouf Univ, Coll Sci, Phys Dept, POB 2014, Sakaka, Saudi Arabia
  • [ 3 ] [Taha, T. A.]Menoufia Univ, Fac Elect Engn, Phys & Engn Math Dept, Menoufia 32952, Egypt
  • [ 4 ] [Amin, Mohammed A.]Taif Univ, Coll Sci, Dept Chem, POB 11099, At Taif 21944, Saudi Arabia
  • [ 5 ] [Irfan, Ahmad]King Khalid Univ, Fac Sci, Dept Chem, POB 9004, Abha 61413, Saudi Arabia
  • [ 6 ] [Oliva, J.]Inst Postosino Invest Cient & Tecnol AC, CONACyT Div Mat Avanzados, San Luis Potosi 78216, San Luis Potosi, Mexico
  • [ 7 ] [Al-Hadeethi, Yas]King Abdulaziz Univ, Fac Sci, Dept Phys, Jeddah 21589, Saudi Arabia
  • [ 8 ] [Al-Hadeethi, Yas]King Abdulaziz Univ, Deanship Sci Res, Lithog Devices Fabricat Res Grp, Jeddah 21589, Saudi Arabia
  • [ 9 ] [Palamanit, Arkom]Prince Songkla Univ, Fac Engn, Dept Specialized Engn, Energy Technol Program, 15 Karnjanavanich Rd, Hat Yai 90110, Songkhla, Thailand
  • [ 10 ] [Khan, Muhammad]Northwestern Polytech Univ, Sch Mat Sci & Engn, Xian, Shaanxi, Peoples R China
  • [ 11 ] [Hayat, Asif]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 12 ] [Mane, Sunil Kumar Baburao]Khaja Bandanawaz Univ, Dept Chem, Gulbarga 585101, Karnataka, India
  • [ 13 ] [Sohail, Muhammad]Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313001, Peoples R China

Reprint 's Address:

  • ASIF HAYAT

    [Hayat, Asif]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China;;[Mane, Sunil Kumar Baburao]Khaja Bandanawaz Univ, Dept Chem, Gulbarga 585101, Karnataka, India;;[Sohail, Muhammad]Univ Elect Sci & Technol China, Yangtze Delta Reg Inst Huzhou, Huzhou 313001, Peoples R China

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Source :

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

ISSN: 1010-6030

Year: 2022

Volume: 423

4 . 3

JCR@2022

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 28

SCOPUS Cited Count: 29

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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