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( )Lanthanide (Ln(3+))-doped near infrared (NIR)-II luminescent nanoprobes have shown great promise in many technological fields, but are currently limited by the low absorption efficiency of Ln(3+) due to the forbidden 4f -> 4f transition. Herein, we report a novel NIR-II luminescent nanoprobe based on efficient energy transfer from Ce3+ to Er3+ and Nd3+ in sub-10 nm SrS nanocrystals (NCs), which are excitable by using a commercial blue light-emitting diode (LED). Through sensitization by the allowed 4f -> 5d transition of Ce3+, the NCs exhibit strong NIR-II luminescence from Er3+ and Nd3+ with quantum yields of 2.9% and 2.3%, respectively. Furthermore, by utilizing the intense NIR-II luminescence of Er3+ from the thermally coupled Stark sublevels of I-1(13/2), we demonstrate the application of SrS:Ce3+/Er3+ NCs as blueLED-excitable NIR-II luminescent nanoprobes for ratiometric thermal sensing. These findings reveal the unique advantages of SrS:Ln(3+) NCs in NIR-II luminescence, which may open up a new avenue for exploring novel and versatile luminescent nanoprobes based on Ln(3+)-doped sulphide NCs.
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SCIENCE CHINA-MATERIALS
ISSN: 2095-8226
CN: 10-1236/TB
Year: 2021
Issue: 4
Volume: 65
Page: 1094-1102
8 . 6 4
JCR@2021
6 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:142
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: