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author:

Chen-Hao, Ou yang (Chen-Hao, Ou yang.) [1] | Zi-Juan, Wei (Zi-Juan, Wei.) [2] | Liang, He (Liang, He.) [3] | Yu-Jun, Guo (Yu-Jun, Guo.) [4] | Ming-Bu, Luo (Ming-Bu, Luo.) [5] | Qi-Pu, Lin (Qi-Pu, Lin.) [6]

Indexed by:

SCIE CSCD

Abstract:

Two pyrazole-based zinc(II) metal-organic frameworks, [(Zn-4(PDC)(2)(BDC)(H2O)(2)]n (compound 1, PDC = 1H-pyrazole-3,5-dicarboxylic acid, BDC = benzene-1,4,-dicarboxylic acid) and [(Zn-3(PDC)(2)(BPY)(3)(H2O)(2)]n (compound 2, BPY = 4,4-bipyridine), were synthesized and characterized by X-ray diffraction, elemental analysis, thermogravimetric analysis, infrared and fluorescence spectroscopy. Compound 1 crystallizes in space group Pna2(1) with a = 14.325(3), b = 10.004(2), c = 16.454(3) angstrom, V = 2357.8(8) angstrom 3, Z = 4, Mr = 821.83, D-c = 2.298 g.cm(-3), F(000) = 1608, GOOF = 1.163, the final R = 0.0218 and wR = 0.0686 for 5150 observed reflections with I > 2 sigma(I). Compound 2 crystallizes in monoclinic space group C2/c with a = 17.034(2), b = 11.6313(9), c = 11.7608(13) angstrom, V = 2034.9(4) angstrom(3), Z = 2, M-r = 1006.91, D-c = 1.643 g.cm(-3), F(000) = 1020, GOOF = 1.084, the final R = 0.0320 and wR = 0.0768 for 2435 observed reflections with I > 2 sigma(I).

Keyword:

luminescence metal-organic frameworks pyrazole-carboxyl X-ray crystallography

Community:

  • [ 1 ] [Chen-Hao, Ou yang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zi-Juan, Wei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Chen-Hao, Ou yang]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
  • [ 4 ] [Zi-Juan, Wei]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
  • [ 5 ] [Liang, He]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
  • [ 6 ] [Yu-Jun, Guo]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
  • [ 7 ] [Ming-Bu, Luo]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
  • [ 8 ] [Qi-Pu, Lin]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Qi-Pu, Lin]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2021

Issue: 10

Volume: 40

Page: 1265-1270

0 . 8 4 7

JCR@2021

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:4

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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