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author:

Zheng, Xiaohai (Zheng, Xiaohai.) [1] | Cai, Jiaming (Cai, Jiaming.) [2] | Zhao, Wentao (Zhao, Wentao.) [3] | Liang, Shijing (Liang, Shijing.) [4] (Scholars:梁诗景) | Zheng, Yong (Zheng, Yong.) [5] (Scholars:郑勇) | Cao, Yanning (Cao, Yanning.) [6] (Scholars:曹彦宁) | Shen, Lijuan (Shen, Lijuan.) [7] | Xiao, Yihong (Xiao, Yihong.) [8] (Scholars:肖益鸿) | Jiang, Lilong (Jiang, Lilong.) [9] (Scholars:江莉龙)

Indexed by:

SCIE CSCD

Abstract:

Being abundant and active, Fe2O3 is suitable for selective oxidation of H2S. However, its practical application is limited due to the poor sulfur selectivity and rapid deactivation. Herein, we report a facile template-free hydrothermal method to fabricate porous alpha-Fe2O3/SnO2 composites with hierarchical nanoflower that can obviously improve the catalytic performance of Fe2O3. It was disclosed that the synergistic effect between alpha-Fe2O3 and SnO2 promotes the physico-chemical properties of alpha-Fe2O3/SnO2 composites. Specifically, the electron transfer between the Fe2+/Fe3+ and Sn2+/Sn4+ redox couples enhances the reducibility of alpha-Fe2O3/SnO2 composites. The number of oxygen vacancies is improved when the Fe cations incorporate into SnO2 structure, which facilitates the adsorption and activation of oxygen species. Additionally, the porous structure improves the accessibility of H2S to active sites. Among the composites, Fe1Sn1 exhibits complete H2S conversion with 100% sulfur selectivity at 220 degrees C, better than those of pure alpha-Fe2O3 and SnO2. Moreover, Fe1Sn1 catalyst shows high stability and water resistance. (C) 2021 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Keyword:

Fe2O3/SnO2 composites H2S selective oxidation Hierarchical structure Oxygen vacancy Synergistic effect

Community:

  • [ 1 ] [Zheng, Xiaohai]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Cai, Jiaming]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Zhao, Wentao]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Liang, Shijing]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Zheng, Yong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 6 ] [Cao, Yanning]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 7 ] [Shen, Lijuan]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 8 ] [Xiao, Yihong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 9 ] [Jiang, Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 梁诗景 沈丽娟

    [Liang, Shijing]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China;;[Shen, Lijuan]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

CHINESE CHEMICAL LETTERS

ISSN: 1001-8417

CN: 11-2710/O6

Year: 2021

Issue: 7

Volume: 32

Page: 2143-2150

8 . 4 5 5

JCR@2021

9 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 26

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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