Highly　efficient　photodriven　conversion　from　biomass-derived　platform　chemicals　to　value-added　chemical　feedstocks　and　clean　fuel　hydrogen　(H2)　possesses　immense　potential　to　cope　with　the　existing　energy　and　environmental　problems.　We　herein　report　a　facile　approach　combining　hydrothermal　method　and　photodeposition　method　for　fabricating　diverse　sulfide-based　cocatalysts　(MoS2,　NiS　and　WS2)　decorated　ZnIn2S4　(ZIS)　for　simultaneous　exploitation　of　photogenerated　electrons　and　holes,　effectively　achieving　the　oxidation　of　furfuryl　alcohol　(FOL)　cooperative　with　H2　evolution　in　one　photoredox　cycle.　The　results　show　the　optimal　binary　MoS2-ZIS　composites　can　obtain　almost　7　times　yield　of　products　(furfural　and　H2)　as　high　as　that　of　blank　ZIS.　Notably,　compared　with　previous　reports　in　literatures,　our　present　MoS2-ZIS　shows　the　best　performance　in　this　photoredox　dual　reaction.　As　a　relay　station　for　electrons,　cocatalysts　facilitate　the　separation　and　transfer　of　photogenerated　charge　carriers　in　the　composites,　therefore　prominently　improving　the　photocatalytic　performance.　We　anticipate　that　the　present　work　can　offer　insights　to　guide　the　design　of　photoredox　reaction　systems　for　efficient　valorization　of　biomass-derived　platform　chemicals.　©　2021　Elsevier　B.V.