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Using butyl sodium xanthate and dichloroethane as raw materials, a new chalcopyrite collector o-butyl S-(1-chloroethyl) dithiocarbonate (GC-) was synthesized. Gas chromatography and infrared spectroscopy analysis show that the agent is a lipid collector with a purity of 90.88%. The pure mineral flotation test compares the collection effect of the new agent GC- and the commonly used sulfide ore collectors on chalcopyrite and pyrite. The results show that, under the flotation conditions at the slurry pH of 7 and the slurry dosage of 160 mg/L, GC- can directly float 96.5% of chalcopyrite, and the recovery rate of pyrite is only 12%, which reflects the high selectivity of the new agent GC- to chalcopyrite. The flotation comparison test of the actual ore of Duobaoshan Copper Mine using GC- and butyl xanthate show that, under the same conditions, the recovery rates of the two agents for copper are similar. Using GC- as the collector, the grade of ore copper increases by 17.14%. FT-IR spectroscopy analysis show that GC- is chemically adsorbed on the surface of chalcopyrite and physically adsorbed on the surface of pyrite, which can achieve better separation of copper and sulfur. The adsorption capacity test results show that, when the pH value is 7, the adsorption capacity of GC- on the surface of chalcopyrite reaches the maximum value, and the adsorption capacity on the surface of pyrite is less. The change trend of adsorption capacity is consistent with the pure mineral flotation test. © 2021, Science Press. All right reserved.
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Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
Year: 2021
Issue: 5
Volume: 31
Page: 1369-1376
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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