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author:

Fan, Jianming (Fan, Jianming.) [1] | Xiong, Jinhua (Xiong, Jinhua.) [2] | Liu, Dayue (Liu, Dayue.) [3] | Tang, Yuanping (Tang, Yuanping.) [4] | He, Song (He, Song.) [5] | Hu, Zhibiao (Hu, Zhibiao.) [6]

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EI

Abstract:

A novel strategy was developed to fabricate a CdS/Pt photocatalyst (defined as CdS/w%Pt-PAR)viathe cathodic photocorrosion effect of CdS. A tentative mechanism for Pt deposition on CdSviathe cathodic photocorrosion effect was proposed, based on a series of electrochemical characterization methods, such as cyclic voltammetry and Mott-Schottky tests. Transmission electron microscopy verified that Pt was grafted on the CdS surfaceviaa heterojunction. Moreover, a strong interaction between Pt and CdS was further confirmed by X-ray photoelectron spectroscopy. The optimal photocatalytic H2evolution rate of CdS/2%Pt-PAR was 1086.1 μmol h−1, 6.4 and 2.6 fold higher than that of the reference samples synthesized by traditional photodeposition (CdS/2%Pt-PD) and chemical reduction (CdS/2%Pt-CR) methods, respectively. Linear sweep voltammetry and fluorescence experiments verified that CdS/2%Pt-PAR has a lower H2evolution overpotential and faster separation of photogenerated carriers, respectively, compared with CdS/2%Pt-PD and CdS/2%Pt-CR. This work paves a new route for fabricating CdS/metal photocatalysts with highly efficient and stable photocatalytic H2evolution activity. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.

Keyword:

Cadmium sulfide Cyclic voltammetry Heterojunctions High resolution transmission electron microscopy Hydrogen II-VI semiconductors Photocatalytic activity Platinum X ray photoelectron spectroscopy

Community:

  • [ 1 ] [Fan, Jianming]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China
  • [ 2 ] [Xiong, Jinhua]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China
  • [ 3 ] [Xiong, Jinhua]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou; 350002, China
  • [ 4 ] [Liu, Dayue]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China
  • [ 5 ] [Tang, Yuanping]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China
  • [ 6 ] [He, Song]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China
  • [ 7 ] [Hu, Zhibiao]Fujian Provincial Key Laboratory of Clean Energy Materials, Longyan University, Longyan; 364000, China

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Source :

New Journal of Chemistry

ISSN: 1144-0546

Year: 2021

Issue: 23

Volume: 45

Page: 10315-10324

3 . 9 2 5

JCR@2021

2 . 7 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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