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author:

Zhou, Jiangcong (Zhou, Jiangcong.) [1] | Chen, Mengting (Chen, Mengting.) [2] | Li, Baojuan (Li, Baojuan.) [3] | Lin, Long (Lin, Long.) [4] | Wang, Bo (Wang, Bo.) [5] | Wu, Dewu (Wu, Dewu.) [6] | Ding, Jianyan (Ding, Jianyan.) [7] | Wu, Quansheng (Wu, Quansheng.) [8]

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Abstract:

Whitlockite β-Ca3(PO4)2-type materials have multiple crystallographic sites for occupying by rare earth ions to achieve a strong and broadband emitting covering the spectra from cyan to deep red and various abundant heterogeneous substitution ability to develop new luminescent materials. In this work, a broadband emitting Sr8MgGa(PO4)7:Eu2+ (SMGP) phosphor, deriving from β-Ca3(PO4)2 host by cations substitution, was prepared by solid state reaction at high temperature. Based on the Rietveld refinement results, SMGP host possesses a monoclinic system with a space group C2/m. The optimized doping concentration was determined to be 0.04. The SMGP: 0.04Eu2+ sample exhibit strong absorption at the wavelength of 250–500 nm, and a broadband emission from 450 to 800 nm covering the spectra from cyan to deep red. However, the SMGP: 0.04Eu2+ phosphors exhibit poor thermal stability with activation energy as 0.156 eV. By adjusting the composition of the trivalent ions Ga3+/Lu3+, controllable emission color from green to yellow can be achieved in the Sr8MgGa1-xLux(PO4)7:Eu2+ solid solution phosphors. Finally, a white light-emitting diodes (LED) lamp was prepared by coating the mixtures of SMGP: 0.04Eu2+ phosphors and BaMgAl10O17:Eu2+ phosphors on the surface of 400 nm near-ultraviolet chip. The optimized white LED lamp exhibits a correlated color temperature of 2991 K and a good color rendering index of 90.2. These results demonstrate the commercialized prospect of SMGP: Eu2+ materials as a broadband emitting phosphor for application in solid state lighting. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.

Keyword:

Activation energy Calcium compounds Color High temperature applications Light emission Light emitting diodes Metal ions Phosphors Rare earths Rietveld refinement Solid state reactions

Community:

  • [ 1 ] [Zhou, Jiangcong]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 2 ] [Zhou, Jiangcong]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 3 ] [Chen, Mengting]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 4 ] [Chen, Mengting]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China
  • [ 5 ] [Li, Baojuan]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 6 ] [Lin, Long]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 7 ] [Wang, Bo]School of Applied Physics and Materials, Wuyi University, Guangdong; 529020, China
  • [ 8 ] [Wu, Dewu]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 9 ] [Ding, Jianyan]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 10 ] [Wu, Quansheng]College of Chemistry and Materials Science, Longyan University, Fujian; 364000, China
  • [ 11 ] [Wu, Quansheng]College of Materials Science and Engineering, Fuzhou University, Fujian; 350108, China

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Source :

Applied Physics A: Materials Science and Processing

ISSN: 0947-8396

Year: 2021

Issue: 5

Volume: 127

2 . 9 8 3

JCR@2021

2 . 5 0 0

JCR@2023

ESI HC Threshold:87

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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