Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: Stereo-controlled assembly and catalysis - Details

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By　varying　the　metal/ligand　ratio,　either　dinuclear　triple　helicates　(ΛΛ/ΔΔ-La2LR/S3)　or　mononuclear　pincer　complexes　(Λ/Δ-LaLR/S)　can　be　stereo-selectively　obtained　from　the　same　chiral　bis-tridentate　ligand　(LR/S).　Due　to　the　open　metal　sites　available　in　both　complexes,　their　catalytic　properties　have　been　demonstrated　with　the　asymmetric　Friedel-Crafts　alkylation　reactions.　©　2021　the　Partner　Organisations.

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[ 1 ] [Chen, Ran]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 2 ] [Chen, Ran]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 3 ] [Yan, Qian-Qian]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 4 ] [Yan, Qian-Qian]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 5 ] [Hu, Shao-Jun]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 6 ] [Hu, Shao-Jun]University of Chinese Academy of Sciences, Beijing; 100049, China
[ 7 ] [Guo, Xiao-Qing]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 8 ] [Guo, Xiao-Qing]University of Chinese Academy of Sciences, Beijing; 100049, China
[ 9 ] [Cai, Li-Xuan]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 10 ] [Yan, Dan-Ni]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 11 ] [Yan, Dan-Ni]University of Chinese Academy of Sciences, Beijing; 100049, China
[ 12 ] [Zhou, Li-Peng]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 13 ] [Sun, Qing-Fu]College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 14 ] [Sun, Qing-Fu]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 15 ] [Sun, Qing-Fu]University of Chinese Academy of Sciences, Beijing; 100049, China

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Source ：

Organic Chemistry Frontiers

ISSN： 2052-4110

Year： 2021

Issue： 11

Volume： 8

Page： 2576-2582

5 . 4 5 6

JCR@2021

4 . 6 0 0

JCR@2023

ESI HC Threshold：117

JCR Journal Grade：1

CAS Journal Grade：1

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WoS CC Cited Count：

SCOPUS Cited Count： 11

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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