In　this　study,　an　oxygenated　carbon　nanotubes　cages　(OCNTCs)　material　was　prepared　by　calcinating　zeolitic　imidazole　framework-67　(ZIF-67)　and　then　oxidizing　the　resulting　material.　The　OCNTCs　was　used　as　a　high　efficient　solid-phase　microextraction　(SPME)　coating　to　extract　aromatic　amines　(AAs).　The　obtained　fiber　exhibited　high　selectivity　for　AAs　over　other　organic　compounds　in　food　contact　materials　(FCMs)　due　to　matched　pore　size　and　abundant　oxygen-containing　groups.　Subsequently,　coupled　with　gas　chromatography-tandem　mass　spectrometry　(GC-MS/MS),　a　sensitive　method　with　low　limits　of　detection　(0.1-2.0　ng　L−1),　wide　linear　ranges　(0.5-500　ng　L　−1)　and　good　precision　(RSDs　≤　8.6%)　was　developed　for　analysis　of　AAs.　The　specific　migrated　AAs　from　food　simulants　that　prepared　by　standardized　migration　and　thermal　migration　test　were　successfully　analysed　by　this　developed　method　with　satisfactory　recoveries　(81.6%　-　118.1%)　and　precision　(RSDs,　2.1-9.5%).　The　results　demonstrated　that　the　prepared　OCNTCs-coated　fibers　displayed　excellent　extraction　performance,　suggesting　a　promising　application　to　investigate　the　migration　behaviors　of　AAs.　©　2021