Desulfonylative Electrocarboxylation with Carbon Dioxide - Details

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Abstract：

Electrocarboxylation　of　organic　halides　is　one　of　the　most　investigated　electrochemical　approaches　for　converting　thermodynamically　inert　carbon　dioxide　(CO2)　into　value-added　carboxylic　acids.　By　converting　organic　halides　into　their　sulfone　derivatives,　we　have　developed　a　highly　efficient　electrochemical　desulfonylative　carboxylation　protocol.　Such　a　strategy　takes　advantage　of　CO2as　the　abundant　C1　building　block　for　the　facile　preparation　of　multifunctionalized　carboxylic　acids,　including　the　nonsteroidal　anti-inflammatory　drug　ibuprofen,　under　mild　reaction　conditions.　©　2021　American　Chemical　Society

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Carbon dioxide Carboxylation Carboxylic acids Drug products

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[ 1 ] [Zhong, Jun-Song]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 2 ] [Yang, Zi-Xin]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 3 ] [Ding, Cheng-Lin]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 4 ] [Huang, Ya-Feng]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 5 ] [Zhao, Yi]BayRay Innovation Center, Shenzhen Bay Laboratory (SZBL), Guangdong; 518000, China
[ 6 ] [Yan, Hong]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 7 ] [Ye, Ke-Yin]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 8 ] [Ye, Ke-Yin]State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen; 361005, China

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2021

Issue： 22

Volume： 86

Page： 16162-16170

4 . 1 9 8

JCR@2021

3 . 4 0 0

JCR@2023

ESI HC Threshold：117

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 39

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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