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author:

Huang, Xiao-Hui (Huang, Xiao-Hui.) [1] | Huang, Xiao-Xing (Huang, Xiao-Xing.) [2] | Ying, Shao-Ming (Ying, Shao-Ming.) [3] | Gong, Zhi-Hui (Gong, Zhi-Hui.) [4] | Gao, Xiao-Mei (Gao, Xiao-Mei.) [5] | Bi, Wen-Chao (Bi, Wen-Chao.) [6] | Chen, Yi-Ping (Chen, Yi-Ping.) [7] | Sun, Yan-Qiong (Sun, Yan-Qiong.) [8]

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EI

Abstract:

Two polyoxometalate-phosphonate compounds with the formular (TBA)2(Hbiz)2 [(C3H5O2P)2Mo5O21]•05H2O (1) and [Ni(2,2′bpy)3]2[(C6H5P)2Mo5O21]•3H2O (2) (TBA=tetrabutylammonium, biz=benzimidazole, bpy=bipyridine) have been synthesized under hydrothermal condition and structurally determined by single-crystal X-ray diffraction. Compound 1 and 2 are Strandberg-type polyoxometalate. The compounds were characterized by various means containing elemental analysis, PXRD, IR and thermal gravimetric analysis. Additionally, their photocatalytic degradation properties toward rhodamine-B are investigated. Compound 2 as catalyst has higher photocatalytic degradation of RhB than 1 due to its larger porosity. Results of the experiment on antitumor activities in vitro showed that two compounds inhibited five different human cancer cells (gastric cancer cells, HGC-27 and SNU668; liver cancer cells, Huh7; and colon cancer cells, HCT116 and SW480) demonstrated dose dependency and selectivity. The relationship between structure and biology activity indicate that inorganic and organic segments may influence the antitumor activity, the introduction of biz and 3-phosphonopropionic acid into P2Mo5 can make compound 1 better antitumor activities. © 2021

Keyword:

Cells Cytology Diseases Gravimetric analysis Nickel metallography Photocatalytic activity Polyoxometalates Rhodamine B Rhodium compounds Single crystals Thermogravimetric analysis

Community:

  • [ 1 ] [Huang, Xiao-Hui]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 2 ] [Huang, Xiao-Hui]College of Chemistry and Materials, Ningde Normal University, Ningde; 352100, China
  • [ 3 ] [Huang, Xiao-Hui]Fujian Provincial Key Laboratory of Featured and Materials in Biochemical Industry, College of Chemistry and Materials, Ningde Normal University, Ningde; Fujian; 352100, China
  • [ 4 ] [Huang, Xiao-Xing]Fujian Key Laboratory of Tumor Microbiology, Department of Medical Microbiology, Fujian Medical University, Fuzhou; Fujian; 350002, China
  • [ 5 ] [Ying, Shao-Ming]College of Chemistry and Materials, Ningde Normal University, Ningde; 352100, China
  • [ 6 ] [Ying, Shao-Ming]Fujian Provincial Key Laboratory of Featured and Materials in Biochemical Industry, College of Chemistry and Materials, Ningde Normal University, Ningde; Fujian; 352100, China
  • [ 7 ] [Gong, Zhi-Hui]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 8 ] [Gao, Xiao-Mei]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 9 ] [Bi, Wen-Chao]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 10 ] [Chen, Yi-Ping]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China
  • [ 11 ] [Sun, Yan-Qiong]College of Chemistry, Fuzhou University, Fuzhou; Fujian; 350002, China

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Source :

Journal of Molecular Structure

ISSN: 0022-2860

Year: 2021

Volume: 1233

3 . 8 4 1

JCR@2021

4 . 0 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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