Aniline　derivates　are　widely　used　in　rubber　products　as　anti-aging　agents,　but　their　biological　toxicity　causes　harm　in　the　use　and　recycling　of　rubber　products.　Therefore,　in　this　study,　a　high-performance　poly(3,4,5,6-tetra-fluorophthalonitrile-p-cyclodextrin)(P-TFPN-p-CD)　solid-phase　extraction　(SPE)　adsorbent　was　synthesized　and　applied　to　extract　and　detect　aniline　derivatives　in　rubber　specimens.　After　crosslinking　with　3,4,5,6-tetrafluorophthalonitrile　(TFPN),　the　polymer　exhibited　mesopores　(7.88　nm)　and　a　large　specific　area　(55.2　m2/g).　The　porous　structure　significantly　improved　the　extraction　efficiency　(recovery　was　between　90.1%　and　110.5%)　and　rate　(60%　in　10　s)　of　4　aniline　derivatives　(aniline,　N-ethyl　aniline,　1,2-phenylenediamine,　and　p-phenylenediamine).　With　a　combined　gas　chromatographic-flame　ionization　detector　(GC-FID),　the　extracted　aniline　derivatives　were　accurately　detected　(RSD　=　1.60%　to　9.90%).　Due　to　the　weak　interaction　between　P-TFPN-β-CD　and　analyte,　the　prepared　poly-TFPN-β-CD　SPE　adsorbent　was　regenerated　via　mild　washing　with　methanol.　The　high　absorption　capacities　remained　after　4　extracting-washing　cycles.　The　novel　porous　SPE　adsorbent　showed　good　extracting　and　recycling　performance　for　the　analysis　and　detection　of　aniline　compounds　in　rubber.　Thus,　it　has　good　prospects　for　application　to　improve　detection　efficiency　and　reduce　cost.　©　2021.　All　Rights　Reserved.