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author:

Kong, Ziyan (Kong, Ziyan.) [1] | Liu, Tao (Liu, Tao.) [2] | Hou, Kun (Hou, Kun.) [3] | Guan, Lunhui (Guan, Lunhui.) [4]

Indexed by:

EI SCIE

Abstract:

Developing efficient and stable non-precious metal oxygen reduction reaction (ORR) catalysts in an environmentally benign and economically affordable way is highly desirable but remains challenging. Manganese and nitrogen co-doped porous carbon, Mn-N-C, has recently been studied as a promising electrocatalyst for the ORR, with high catalytic efficiency and long-term stability. In this paper, we report the preparation of a highly active Mn-N-C catalyst using the metal-organic framework ZIF-8 synthesized by a minimal-water-assisted grinding method as the precursor. Due to the mechanical force exerted by the grinding, the manganese salt is finely dispersed on the ZIF-8 framework and formation of manganese oxides upon pyrolysis is efficiently alleviated, and the single-atomic Mn-N-C catalyst was obtained using the mechanochemically synthesized manganese salt-incorporated ZIF-8 as the precursor. Moreover, the minimal-water-assisted mechanochemical method enables the synthesis of manganese-doped ZIF-8 with a high yield compared with the theoretical value and much higher than the yield obtained for the widely used organic solvent synthesis method. The resultant Mn-N-C catalyst delivers a half-wave potential of 0.80 V in 0.1 M HClO4 solution and 0.94 V in 0.1 M KOH solution; excellent stability was also achieved. The Mn-N-C was used as the cathode to assemble a zinc-air battery and a peak power density of 185 mW cm(-2) was achieved, demonstrating its promise as a practical and useable ORR catalyst.

Keyword:

Community:

  • [ 1 ] [Kong, Ziyan]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Liu, Tao]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Hou, Kun]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Kong, Ziyan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Hou, Kun]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China;;[Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

Year: 2022

Issue: 6

Volume: 10

Page: 2826-2834

1 1 . 9

JCR@2022

1 0 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count: 44

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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