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Developing efficient and stable non-precious metal oxygen reduction reaction (ORR) catalysts in an environmentally benign and economically affordable way is highly desirable but remains challenging. Manganese and nitrogen co-doped porous carbon, Mn-N-C, has recently been studied as a promising electrocatalyst for the ORR, with high catalytic efficiency and long-term stability. In this paper, we report the preparation of a highly active Mn-N-C catalyst using the metal-organic framework ZIF-8 synthesized by a minimal-water-assisted grinding method as the precursor. Due to the mechanical force exerted by the grinding, the manganese salt is finely dispersed on the ZIF-8 framework and formation of manganese oxides upon pyrolysis is efficiently alleviated, and the single-atomic Mn-N-C catalyst was obtained using the mechanochemically synthesized manganese salt-incorporated ZIF-8 as the precursor. Moreover, the minimal-water-assisted mechanochemical method enables the synthesis of manganese-doped ZIF-8 with a high yield compared with the theoretical value and much higher than the yield obtained for the widely used organic solvent synthesis method. The resultant Mn-N-C catalyst delivers a half-wave potential of 0.80 V in 0.1 M HClO4 solution and 0.94 V in 0.1 M KOH solution; excellent stability was also achieved. The Mn-N-C was used as the cathode to assemble a zinc-air battery and a peak power density of 185 mW cm(-2) was achieved, demonstrating its promise as a practical and useable ORR catalyst.
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JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7488
Year: 2022
Issue: 6
Volume: 10
Page: 2826-2834
1 1 . 9
JCR@2022
1 0 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 35
SCOPUS Cited Count: 44
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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