Exploring　efficient　and　stable　photoanode　materials　is　a　necessary　link　to　realize　the　practical　application　of　solar-driven　photoelectrochemical　(PEC)　water　splitting.　Hence,　we　prepared　rutile　TiO2　nanorods,　with　a　width　of　50　nm,　which　was　growth　in　situ　on　carbon　cloth　(TiO2　@CC)　by　hydrothermal　reaction.　And　then,　Ag　nanoparticles　(NPs)　and　biomass　N,S-C　NPs　were　chosen　for　the　additional　modification　of　the　fabricated　TiO2　nanorods　to　produce　broccoli-like　Ag-N,S-C/TiO2@CC　nanocomposites.　According　to　the　result　of　ultraviolet-visible　diffuse　reflectance　spectroscopy　(UV-vis)　and　PEC　water　splitting　performance　tests,　Ag-N,S-C/TiO2　@CC　broadens　the　absorption　region　of　TiO2@CC　from　the　ultraviolet　region　to　the　visible　region.　Under　AM　1.5G　solar　light　irradiation,　the　photocurrent　density　of　Ag-N,S-CiTiO(2)　@CC　is　89.8　mu　A.cm(-2),　which　is　11.8　times　higher　than　TiO2@CC.　Under　visible　light　irradiation,　the　photocurrent　density　of　Ag-N,S-C/TiO2@CC　reaches　to　12.6　mu　A.cm(-2),　which　is　21.0　times　higher　than　TiO2@CC.　Moreover,　Ag-N,S-C/TiO2@CC　shows　a　photocurrent　responses　in　full　pH　range.　It　can　be　found　that　Ag　NPs　and　N,　S-C　NPs　play　key　roles　in　broaden　the　absorption　range　of　TiO2　nanorods　to　the　visible　light　region　and,　promote　the　occurrence　of　PEC　water　oxidation　reaction　due　to　the　surface　plasmon　resonance　effect　of　Ag　NPs　and　the　synergistic　effect　of　N,S-C　NPs.　The　mechanism　demonstrated　that　Ag-N,S-C/TiO2@CC　can　separate　the　photogenerated　electron-hole　pairs　effectively　and　transfer　the　photogenerated　electrons　to　the　photocathode　(Pt　plate)　in　time.　This　research　provides　a　new　strategy　for　exploration　surface　plasma　metal　coupled　biomass　carbon　materials　in　the　field　of　PEC　water　splitting.　(C)　2021　The　Chemical　Industry　and　Engineering　Society　of　China,　and　Chemical　Industry　Press　Co.,　Ltd.　All　rights　reserved.