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Abstract:
In this paper, a Dy3+:Ca2Al2SiO7 single crystal was grown successfully by the Czochralski technique. The effective segregation coefficient of Dy3+ ions in Dy3+:Ca2Al2SiO7 crystal was measured to be 1.12. The crystal's spectroscopic properties were investigated in detail. The absorption cross sections at 452 nm are 1.03 × 10−21 cm2, and 0.98 × 10−21 cm2 with the full width at half maximum 10.79 and 4.89 nm for π- and σ-polarizations, respectively. Based on the Judd-Ofelt theory, the radiative transition probabilities, fluorescence branching ratios, and radiative lifetime of Dy3+:Ca2Al2SiO7 crystal were obtained. The emission cross sections at 574 nm are 13.82 × 10−21 cm2, and 8.33 × 10−21 cm2 for π- and σ-polarizations, respectively. The fluorescence decay time of 4F9/2 multiplet is 334.9 μs, and the fluorescence quantum efficiency is 58.6%. These results show that Dy3+:Ca2Al2SiO7 crystal is a promising yellow laser material suitable for commercial 450 nm blue laser diode pumping. © 2022 Elsevier B.V.
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Journal of Luminescence
ISSN: 0022-2313
Year: 2022
Volume: 245
3 . 6
JCR@2022
3 . 3 0 0
JCR@2023
ESI HC Threshold:55
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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