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author:

Zhu, Rui (Zhu, Rui.) [1] | Dong, Jianyue (Dong, Jianyue.) [2] | Lin, Ziwei (Lin, Ziwei.) [3] | Lin, Zhoubin (Lin, Zhoubin.) [4]

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EI

Abstract:

In this paper, a Dy3+:Ca2Al2SiO7 single crystal was grown successfully by the Czochralski technique. The effective segregation coefficient of Dy3+ ions in Dy3+:Ca2Al2SiO7 crystal was measured to be 1.12. The crystal's spectroscopic properties were investigated in detail. The absorption cross sections at 452 nm are 1.03 × 10−21 cm2, and 0.98 × 10−21 cm2 with the full width at half maximum 10.79 and 4.89 nm for π- and σ-polarizations, respectively. Based on the Judd-Ofelt theory, the radiative transition probabilities, fluorescence branching ratios, and radiative lifetime of Dy3+:Ca2Al2SiO7 crystal were obtained. The emission cross sections at 574 nm are 13.82 × 10−21 cm2, and 8.33 × 10−21 cm2 for π- and σ-polarizations, respectively. The fluorescence decay time of 4F9/2 multiplet is 334.9 μs, and the fluorescence quantum efficiency is 58.6%. These results show that Dy3+:Ca2Al2SiO7 crystal is a promising yellow laser material suitable for commercial 450 nm blue laser diode pumping. © 2022 Elsevier B.V.

Keyword:

Aluminum compounds Calcium compounds Crystal growth Fluorescence Judd-Ofelt theory Polarization Pumping (laser) Silicon Silicon compounds Single crystals Solid state lasers

Community:

  • [ 1 ] [Zhu, Rui]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 2 ] [Zhu, Rui]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 3 ] [Dong, Jianyue]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 4 ] [Lin, Ziwei]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Lin, Zhoubin]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 6 ] [Lin, Zhoubin]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China

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Source :

Journal of Luminescence

ISSN: 0022-2313

Year: 2022

Volume: 245

3 . 6

JCR@2022

3 . 3 0 0

JCR@2023

ESI HC Threshold:55

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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