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author:

Huang, Haowei (Huang, Haowei.) [1] | Weng, Bo (Weng, Bo.) [2] | Zhang, Hongwen (Zhang, Hongwen.) [3] | Lai, Feili (Lai, Feili.) [4] | Long, Jinlin (Long, Jinlin.) [5] | Hofkens, Johan (Hofkens, Johan.) [6] | Douthwaite, Richard E. (Douthwaite, Richard E..) [7] | Steele, Julian A. (Steele, Julian A..) [8] | Roeffaers, Maarten B. J. (Roeffaers, Maarten B. J..) [9]

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EI

Abstract:

Sunlight is an abundant and clean energy source, the harvesting of which could make a significant contribution to society's increasing energy demands. Metal halide perovskites (MHP) have recently received attention for solar fuel generation through photocatalysis and solar-driven electrocatalysis. However, MHP photocatalysis is limited by low solar energy conversion efficiency, poor stability, and impractical reaction conditions. Compared to photocatalysis, MHP solar-driven electrocatalysis not only exhibits higher solar conversion efficiency but also is more stable when operating under practical reaction conditions. In this Perspective, we outline three leading types of MHP solar-driven electrocatalysis device technologies now in the research spotlight, namely, (1) photovoltaic-electrochemical (PV-EC), (2) photovoltaic-photoelectrochemical (PV-PEC), and (3) photoelectrochemical (PEC) approaches for solar-to-fuel reactions, including water-splitting and the CO2 reduction reaction. In addition, we compare each technology to show their relative technical advantages and limitations and highlight promising research directions for the rapidly emerging scientific field of MHP-based solar-driven electrocatalysis. © 2021 American Chemical Society.

Keyword:

Conversion efficiency Electrocatalysis Fuels Metal halides Perovskite Perovskite solar cells Photocatalysis Solar energy Solar power generation

Community:

  • [ 1 ] [Huang, Haowei]CMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven; 3001, Belgium
  • [ 2 ] [Weng, Bo]CMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven; 3001, Belgium
  • [ 3 ] [Zhang, Hongwen]CMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven; 3001, Belgium
  • [ 4 ] [Lai, Feili]Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee; 3001, Belgium
  • [ 5 ] [Long, Jinlin]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 6 ] [Hofkens, Johan]Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Heverlee; 3001, Belgium
  • [ 7 ] [Douthwaite, Richard E.]Department of Chemistry, University of York, York; YO10 5DD, United Kingdom
  • [ 8 ] [Steele, Julian A.]CMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven; 3001, Belgium
  • [ 9 ] [Roeffaers, Maarten B. J.]CMACS, Department of Microbial and Molecular Systems, KU Leuven, Celestijnenlaan 200F, Leuven; 3001, Belgium

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Source :

Journal of Physical Chemistry Letters

Year: 2022

Issue: 1

Volume: 13

Page: 25-41

5 . 7

JCR@2022

4 . 9 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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