• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wang, Yi-Wen (Wang, Yi-Wen.) [1] | Li, Meng-Hua (Li, Meng-Hua.) [2] | Zhang, Shu-Quan (Zhang, Shu-Quan.) [3] (Scholars:张书泉) | Fang, Xin (Fang, Xin.) [4] (Scholars:方昕) | Lin, Mei-Jin (Lin, Mei-Jin.) [5] (Scholars:林梅金)

Indexed by:

EI SCIE

Abstract:

Donor-acceptor (D-A) hybrid frameworks with visual X-ray photochromism at room temperature are fascinating because of their promising applications as X-ray detectors. Herein, a 3-fold interpenetrated D-A hybrid framework, [Eu(bcbp)(1.5)(DMF)(H2O)(2)][Co(CN)(6)]middot4H(2)OmiddotCH(3)OH (1), has been obtained by incorporating electron-rich Co(CN)(6)(3-) into the electron-deficient europium viologen framework, which interestingly exhibits ultraviolet and low-power X-ray dual photochromism with a remarkable color change from brown to green. Experimental and theoretical studies revealed that the X-ray photochromic behavior of hybrid 1 could be attributed to its D-A hybrid structural feature increasing the extent of photoinduced electron transfer and thus photogenerated radical species upon X-ray irradiation. Meanwhile, due to the introduction of emissive lanthanide cations in the D-A system, hybrid 1 exhibits photomodulated luminescence properties.

Keyword:

Community:

  • [ 1 ] [Wang, Yi-Wen]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 2 ] [Li, Meng-Hua]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 3 ] [Fang, Xin]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 4 ] [Lin, Mei-Jin]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Mei-Jin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Zhang, Shu-Quan]Fuzhou Univ, Coll Zhicheng, Fuzhou 350002, Peoples R China

Reprint 's Address:

Show more details

Related Keywords:

Related Article:

Source :

INORGANIC CHEMISTRY

ISSN: 0020-1669

Year: 2022

Issue: 21

Volume: 61

Page: 8153-8159

4 . 6

JCR@2022

4 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:181/10019458
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1