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author:

Lai, Yuquan (Lai, Yuquan.) [1] | Zhang, Zhaoting (Zhang, Zhaoting.) [2] | Zhang, Zeyi (Zhang, Zeyi.) [3] | Tan, Yangyang (Tan, Yangyang.) [4] | Yu, Liyue (Yu, Liyue.) [5] | Wu, Wei (Wu, Wei.) [6] | Wang, Zichen (Wang, Zichen.) [7] | Jiang, Tao (Jiang, Tao.) [8] | Gao, Songhua (Gao, Songhua.) [9] | Cheng, Niancai (Cheng, Niancai.) [10] (Scholars:程年才)

Indexed by:

EI SCIE

Abstract:

Electronic structure design to optimize the hydrogen adsorption/desorption balance on the catalysts plays a key role in improving the catalytic efficiency of the low-load Pt-based catalyst in the hydrogen evolution reaction (HER). In this study, we modulate the electronic structure of Pt nanoclusters through tuning the interface of Pt/SnO2 clusters confined into nitrogen-doped porous carbon for enhanced hydrogen evolution catalysis. Theoretical calculations reveal that adjusting the contact distance between Pt and SnO2 generate stronger electron coupling and more free electrons transfer to Pt, and thus downshift Pt d-band center, which balances the intermediate H* adsorption/desorption on the Pt site, thus accelerating HER catalytic process. As a result, in acidic solution, the optimized catalyst (Pt/SnO2@NPC-300) showed significantly enhanced HER catalytic activity with the minimum overpotential (11.7 mV) at 10 mA.cm(-2), the highest mass activity (4.08 A mg(Pt)(-1))at 10 mV and the turnover frequency (4.13 s(-1)) at 20 mV, far superior to that of Pt/NPC and commercial Pt/C catalyst. Our work provides a reference for the precise design of low-Pt nanocluster catalysts with high HER activity and durability.

Keyword:

Electron transfer Hydrogen evolution catalysis Pt nanoclusters SMSI Tuning the interface

Community:

  • [ 1 ] [Lai, Yuquan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Zhaoting]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang, Zeyi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Tan, Yangyang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Yu, Liyue]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Wu, Wei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Wang, Zichen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Jiang, Tao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Cheng, Niancai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Lai, Yuquan]Sanming Univ, Coll Mech & Elect Engn, Sanming 365004, Peoples R China
  • [ 11 ] [Gao, Songhua]Sanming Univ, Coll Mech & Elect Engn, Sanming 365004, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2022

Volume: 435

1 5 . 1

JCR@2022

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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