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Abstract:
Aggregation-induced emission (AIE) based luminescent materials are generating intensive interest due to their unique fluorescence in the aggregation state. Herein we report a strategy of dynamic covalent chemistry (DCC) controlled AIE luminogens for the regulation of multicolor emission in reversible covalent polymer networks. Tetraphenylethene derived ring-chain tautomers were prepared, and the emission was readily controlled through multimode, such as changing the solvent, adding the base, and dynamic covalent reactions with amines. Moreover, the construction of dynamic covalent cross-linked luminescent hydrogels with tunable fluorescent, self-healing, and mechanical properties, was realized. The combination of AIE and aggregation-caused quenching (ACQ) fluorophores in the polymer network further enabled the realization of a multicolor modulator, including white emission, in both solution and gel states. The strategies and results presented should find utility in dynamic assemblies, polymer networks, chemical sensing, and responsive materials. (C) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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CHINESE CHEMICAL LETTERS
ISSN: 1001-8417
CN: 11-2710/O6
Year: 2022
Issue: 6
Volume: 33
Page: 3267-3271
9 . 1
JCR@2022
9 . 4 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 16
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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