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author:

Zheng, Yun (Zheng, Yun.) [1] | Zhang, Lili (Zhang, Lili.) [2] | Li, Yuke (Li, Yuke.) [3] | Wang, Yayun (Wang, Yayun.) [4] | Chen, Jingling (Chen, Jingling.) [5] | Lin, Bizhou (Lin, Bizhou.) [6] | Zheng, Yanzhen (Zheng, Yanzhen.) [7] | Cheng, Lin (Cheng, Lin.) [8] | Wang, Sibo (Wang, Sibo.) [9] (Scholars:汪思波) | Chen, Yilin (Chen, Yilin.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Polymeric carbon nitride (CN) has evoked considerable attention in photocatalysis, however, its p- deficiency conjugated frameworks engendering weak visible-light absorption and rapid charge recombi-nation hinder the practical utilizations. Herein, a novel donor & ndash;acceptor (D-A) conjugated polymer based on triptycene incorporated carbon nitride (T-CN) has been facilely prepared by thermal copolymerization of melamine and 2,6,14-triaminotriptycene. Combined with the density functional theory (DFT) calcula-tions, it is found that the formation of intramolecular charge transfer and the extended p-conjugative effect in the D-A structure contribute to a broadened light-harvesting spectral range, a higher charge sep-aration/transfer efficiency and more active sites of T-CN for photoredox reactions. The T-CN catalyst accomplished superior visible-light photocatalytic performance in both hydrogen evolving and carbon dioxide reduction. The optimal T-CN catalyst exhibited the highest hydrogen evolution rate of 80.9 +/- 1. 3 & micro;mol center dot h-1 and carbon monoxide production rate of 8.1 +/- 0.2 & micro;mol center dot h-1, which are ca. 8-fold and 20 fold of bulk CN, respectively. The convenient strategy of constructing D-A conjugated structure opens up a new intriguing avenue toward the rational creation of efficient polymeric nanomaterials for versatile applications of solar fuel production. (c) 2022 Elsevier Inc. All rights reserved. Superscript/Subscript Available</comment

Keyword:

Carbon dioxide reduction Carbon nitride Hydrogen evolution Photocatalysis Triptycene

Community:

  • [ 1 ] [Zheng, Yun]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 2 ] [Zhang, Lili]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 3 ] [Wang, Yayun]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 4 ] [Chen, Jingling]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 5 ] [Lin, Bizhou]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 6 ] [Cheng, Lin]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 7 ] [Chen, Yilin]Huaqiao Univ, Xiamen Key Lab Optoelect Mat & Adv Mfg, Coll Mat Sci & Engn, Xiamen 361021, Fujian, Peoples R China
  • [ 8 ] [Zheng, Yanzhen]Jimei Univ, Coll Ocean Food & Biol Engn, Xiamen 361021, Peoples R China
  • [ 9 ] [Wang, Sibo]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 10 ] [Li, Yuke]Chinese Univ Hong Kong, Dept Chem & Ctr Sci Modeling & Computat, Shatin, Hong Kong, Peoples R China

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Source :

JOURNAL OF COLLOID AND INTERFACE SCIENCE

ISSN: 0021-9797

Year: 2022

Volume: 622

Page: 675-689

9 . 9

JCR@2022

9 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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