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Polymeric carbon nitride (CN) has evoked considerable attention in photocatalysis, however, its p- deficiency conjugated frameworks engendering weak visible-light absorption and rapid charge recombi-nation hinder the practical utilizations. Herein, a novel donor & ndash;acceptor (D-A) conjugated polymer based on triptycene incorporated carbon nitride (T-CN) has been facilely prepared by thermal copolymerization of melamine and 2,6,14-triaminotriptycene. Combined with the density functional theory (DFT) calcula-tions, it is found that the formation of intramolecular charge transfer and the extended p-conjugative effect in the D-A structure contribute to a broadened light-harvesting spectral range, a higher charge sep-aration/transfer efficiency and more active sites of T-CN for photoredox reactions. The T-CN catalyst accomplished superior visible-light photocatalytic performance in both hydrogen evolving and carbon dioxide reduction. The optimal T-CN catalyst exhibited the highest hydrogen evolution rate of 80.9 +/- 1. 3 & micro;mol center dot h-1 and carbon monoxide production rate of 8.1 +/- 0.2 & micro;mol center dot h-1, which are ca. 8-fold and 20 fold of bulk CN, respectively. The convenient strategy of constructing D-A conjugated structure opens up a new intriguing avenue toward the rational creation of efficient polymeric nanomaterials for versatile applications of solar fuel production. (c) 2022 Elsevier Inc. All rights reserved. Superscript/Subscript Available</comment
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN: 0021-9797
Year: 2022
Volume: 622
Page: 675-689
9 . 9
JCR@2022
9 . 4 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 15
SCOPUS Cited Count: 17
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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