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author:

Chen, Taoran (Chen, Taoran.) [1] | Li, Mengqing (Li, Mengqing.) [2] | Shen, Lijuan (Shen, Lijuan.) [3] | Roeffaers, Maarten B. J. (Roeffaers, Maarten B. J..) [4] | Weng, Bo (Weng, Bo.) [5] | Zhu, Haixia (Zhu, Haixia.) [6] | Chen, Zhihui (Chen, Zhihui.) [7] | Yu, Dan (Yu, Dan.) [8] | Pan, Xiaoyang (Pan, Xiaoyang.) [9] | Yang, Min-Quan (Yang, Min-Quan.) [10] | Qian, Qingrong (Qian, Qingrong.) [11]

Indexed by:

SCIE

Abstract:

Metal halide perovskites (MHPs) have been widely investigated for various photocatalytic applications. However, the dual-functional reaction system integrated selective organic oxidation with H-2 production over MHPs is rarely reported. Here, we demonstrate for the first time the selective oxidation of aromatic alcohols to aldehydes integrated with hydrogen (H-2) evolution over Pt-decorated CsPbBr3. Especially, the functionalization of CsPbBr3 with graphene oxide (GO) further improves the photoactivity of the perovskite catalyst. The optimal amount of CsPbBr3/GO-Pt exhibits an H-2 evolution rate of 1,060 mu mol g(-1) h(-1) along with high selectivity (>99%) for benzyl aldehyde generation (1,050 mu mol g(-1) h(-1)) under visible light (lambda > 400 nm), which is about five times higher than the CsPbBr3-Pt sample. The enhanced activity has been ascribed to two effects induced by the introduction of GO: 1) GO displays a structure-directing role, decreasing the particle size of CsPbBr3 and 2) GO and Pt act as electron reservoirs, extracting the photogenerated electrons and prohibiting the recombination of the electron-hole pairs. This study opens new avenues to utilize metal halide perovskites as dual-functional photocatalysts to perform selective organic transformations and solar fuel production.

Keyword:

anaerobic oxidation of aromatic alcohols CsPbBr3 graphene oxide H2 production perovskite photocatalysis

Community:

  • [ 1 ] [Chen, Taoran]Fujian Normal Univ, Coll Environm Sci & Engn, Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou, Peoples R China
  • [ 2 ] [Li, Mengqing]Fujian Normal Univ, Coll Environm Sci & Engn, Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou, Peoples R China
  • [ 3 ] [Shen, Lijuan]Fujian Normal Univ, Coll Environm Sci & Engn, Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou, Peoples R China
  • [ 4 ] [Yang, Min-Quan]Fujian Normal Univ, Coll Environm Sci & Engn, Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou, Peoples R China
  • [ 5 ] [Qian, Qingrong]Fujian Normal Univ, Coll Environm Sci & Engn, Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou, Peoples R China
  • [ 6 ] [Roeffaers, Maarten B. J.]CMACS, Dept Microbial & Mol Syst, Leuven, Belgium
  • [ 7 ] [Weng, Bo]CMACS, Dept Microbial & Mol Syst, Leuven, Belgium
  • [ 8 ] [Zhu, Haixia]Cent South Univ, Sch Phys & Elect, Hunan Key Lab Nanophonon & Devices, Changsha, Peoples R China
  • [ 9 ] [Chen, Zhihui]Cent South Univ, Sch Phys & Elect, Hunan Key Lab Nanophonon & Devices, Changsha, Peoples R China
  • [ 10 ] [Yu, Dan]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou, Peoples R China
  • [ 11 ] [Pan, Xiaoyang]Quanzhou Normal Univ, Coll Chem Engn & Mat, Quanzhou, Peoples R China

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Source :

FRONTIERS IN CHEMISTRY

ISSN: 2296-2646

Year: 2022

Volume: 10

5 . 5

JCR@2022

3 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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