A　composite　of　two-dimensional　(2D)　GeSe2　nanosheets　dispersed　on　N-doped　reduced　graphene　oxide　(GeSe2/N-rGO)　is　fabricated　via　a　simple　hydrothermal　method　combined　with　post-selenization　process.　The　high　electronic　conductivity　and　the　substantial　void　spaces　of　the　wrinkled　N-rGO　can　improve　the　electrical　conductivity　of　the　active　material　and　accommodate　the　volume　evolution　of　GeSe2　nanosheets　during　the　(de)lithiation　processes,　while　GeSe2　nanosheets　can　reduce　ion　diffusion　length　effectively.　Meanwhile,　the　unique　layered　structure　is　beneficial　to　the　contact　of　the　active　material　and　electrolyte,　and　the　reversibility　of　conversion　reaction　has　also　been　improved.　Furthermore,　kinetics　analysis　reveals　a　pseudocapacitance-dominated　Li+-storage　mechanism　at　high　rates.　In-situ　X-ray　diffraction　analysis　discloses　that　the　conversion　reaction　has　played　a　certain　part　in　Li+-storage.　Thus,　the　GeSe2/N-rGO　composite　delivers　excellent　rate　capability　and　good　long-term　stability　with　a　high　reversible　capacity　of　711.0　mA　h　g−1　after　2000　cycles　at　1　A　g−1.　©　2022　Wiley-VCH　GmbH.