In　this　work,　a　novel　hierarchical　tubular　structure　(SnO2@NC@MoS2/C)　has　been　designed　and　synthesized　using　MnOx　nanowires　as　a　sacrificing　template　for　the　hollow　tube　and　successively　wrapping　a　SnO2　layer,　nitrogen-doped　carbon　(NC)　layer,　and　ultrathin　MoS2　nanosheets　incorporating　into　a　carbon　layer.　In　such　a　particular　structure,　the　conductivity　of　SnO2　and　MoS2　has　been　obviously　improved,　and　the　large　volume　change　caused　by　the　lithium/sodium-ion　(Li+/Na+)　intercalation/deintercalation　has　also　been　effectively　alleviated.　Especially,　due　to　the　expansion　of　the　spacing　between　MoS2　layers　caused　by　the　outermost　carbon　derived　from　glucose,　the　shuttling　of　Li+/Na+　between　the　layers　becomes　easier.　Thanks　to　the　advantages　mentioned　above,　hierarchical　hollow　nanostructures　feature　the　synergistic　effects　of　different　components,　the　SnO2@NC@MoS2/C　nanocomposite　displays　an　exceptional　discharge　capacity　(980.9　mAh　g-1　at　0.2　Ag-1)　and　long　cycle　stability　(750　mAh　g-1　at　1　Ag-1　for　450　cycles)　when　applied　in　lithium-ion　batteries.　Even　at　2,　5,　and　10　Ag-1,　the　specific　capacities　still　reach　up　to　672.7,　630.1,　and　565　mAh　g-1　after　500　cycles,　respectively,　which　delivers　an　ultrastable　high-rate　cycle　performance.　Meanwhile,　it　also　achieves　eminent　capacity　(479.3　mAh　g-1　at　0.2　Ag-1　over　150　cycles),　small　capacity　attenuation　rate　(0.06%　per　cycle　after　2000　cycles　at　1　Ag-1),　and　superior　rate　capacity　(818.5,　691.6,　577.6,　506.3,　442.4,　and　348.2　mAh　g-1　at　0.1,　0.2,　0.5,　1,　2,　and　5　Ag-1,　respectively)　when　the　composite　used　for　sodium-ion　batteries.　©　2022　American　Chemical　Society.