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author:

Zhao, Si (Zhao, Si.) [1] | Qiu, Ruoxue (Qiu, Ruoxue.) [2] | Su, Jiasheng (Su, Jiasheng.) [3] | Li, Falei (Li, Falei.) [4] | Yanting, Liu (Yanting, Liu.) [5] | Zheng, Lituo (Zheng, Lituo.) [6] | Huang, Yiyin (Huang, Yiyin.) [7] | Wei, Mingdeng (Wei, Mingdeng.) [8] | Hong, Zhensheng (Hong, Zhensheng.) [9]

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EI

Abstract:

Nowadays, the main deficiency in boosting the commercialization of sodium ion battery is the relatively low energy density. Herein, we propose a new way to significantly improve the energy density by constructing low negative/positive (N/P) ratio sodium-based batteries enabled by reversible Na metal electrodeposition on sodiophilic zinc-metal-decorated hard carbons (HC–Zn) anode. HC-Zn is used as a typical insertion anode, and simultaneously as a substrate for Na metal plating, leading to the formation of a composite NaxC-Na metal anode with a hybrid energy storage process. We also provide a general and low-cost method of Zn metal coating on various hard carbons. The compatibility between Zn and Na metal is firstly revealed by molecular dynamics simulations. As a result, HC-Zn electrode exhibits a highly reversibility even at a high-capacity of 1100 mA h g−1 and 5C rate, which can stably cycle 1400 cycles with a high Coulombic efficiency around 100%. Finally, the full cells of HC-Zn anode coupling with sodium vanadyl phosphate cathode with low NP ratio (NP = 0.8 and 0.6) are constructed which display good cycling stability and remarkably improved energy density from 220 Wh/kg of regular NP 1.1 to 286 Wh/kg. © 2022 Elsevier B.V.

Keyword:

Anodes Carbon Metal ions Molecular dynamics Sodium compounds Sodium-ion batteries Vanadium compounds Zinc

Community:

  • [ 1 ] [Zhao, Si]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 2 ] [Zhao, Si]Fujian Provincial Collaborative Innovation Center for Advanced High-Field Superconducting Materials and Engineering, Fuzhou; 350117, China
  • [ 3 ] [Qiu, Ruoxue]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 4 ] [Qiu, Ruoxue]Fujian Provincial Collaborative Innovation Center for Advanced High-Field Superconducting Materials and Engineering, Fuzhou; 350117, China
  • [ 5 ] [Su, Jiasheng]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 6 ] [Li, Falei]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 7 ] [Yanting, Liu]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 8 ] [Zheng, Lituo]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 9 ] [Huang, Yiyin]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 10 ] [Wei, Mingdeng]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Fujian, Fuzhou; 350116, China
  • [ 11 ] [Hong, Zhensheng]Fujian Provincial Key Laboratory of Quantum Manipulation and New Energy Materials, College of Physics and Energy, Fujian Normal University, Fujian, Fuzhou; 350117, China
  • [ 12 ] [Hong, Zhensheng]Academy of Carbon Neutrality of Fujian Normal University, Fuzhou; 350117, China

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2022

Volume: 544

9 . 2

JCR@2022

8 . 1 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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