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author:

Zhang, F. (Zhang, F..) [1] | Weng, Q. (Weng, Q..) [2] | Zhang, Y. (Zhang, Y..) [3] | Ai, N. (Ai, N..) [4] | Jiang, S.P. (Jiang, S.P..) [5] | Guan, C. (Guan, C..) [6] | Shao, Y. (Shao, Y..) [7] | Fang, H. (Fang, H..) [8] | Luo, Y. (Luo, Y..) [9] | Chen, K. (Chen, K..) [10]

Indexed by:

Scopus

Abstract:

Solid oxide fuel cells (SOFCs) are the most efficient energy conversion technology to convert the chemical energy of fuels like hydrogen, natural gas, etc. to electricity. However, one of the limiting factors in the commercial viability of SOFCs technologies is the time-consuming and high-cost multiple cell fabrication processes. Here, we report the development of a facile procedure for the preparation of an electrolyte-supported cell with a Ni-Gd0.1Ce0.9O1.95 composite anode and a La0.6Sr0.4Co0.2Fe0.8O3-δ cathode, and the fabrication procedure of the electrodes decreases from four steps of screen-printing and sintering of conventional cell preparation processes to two steps of screen-printing using a direct assembly approach without the high-temperature sintering steps. The most important observation is the simultaneous formation of the electrode/electrolyte interfaces of both the anode and cathode by in situ passing a current through the directly assembled cells at 800 ℃. The power density of the directly assembled cell reaches 0.41 W cm−2 at a voltage of 0.7 V and 800 ℃, close to 0.46 W cm−2 of the sintered cell. The directly assembled cell shows comparable operational stability to the sintered cell at 800 ℃ for 100 h. This work sheds light on the facile fabrication of electrolyte-supported cells with substantially simplified preparation procedures and reduced costs. © 2022

Keyword:

Direct assembly; Electrochemical polarization; Electrode/electrolyte interface; Solid oxide fuel cell

Community:

  • [ 1 ] [Zhang, F.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 2 ] [Weng, Q.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 3 ] [Zhang, Y.]National Key Laboratory for Precision Hot Processing of Metals, MIIT Key Laboratory of Advanced Structure-Function Integrated Materials and Green Manufacturing Technology, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China
  • [ 4 ] [Ai, N.]Fujian College Association Instrumental Analysis Center, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 5 ] [Jiang, S.P.]WA School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia
  • [ 6 ] [Guan, C.]Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China
  • [ 7 ] [Shao, Y.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 8 ] [Fang, H.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Luo, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou, 350002, China
  • [ 10 ] [Chen, K.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China

Reprint 's Address:

  • [Guan, C.]Key Laboratory of Interfacial Physics and Technology, China

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Source :

Electrochimica Acta

ISSN: 0013-4686

Year: 2022

Volume: 424

6 . 6

JCR@2022

5 . 5 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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