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author:

Lee, Chou-Yuan (Lee, Chou-Yuan.) [1] | Wu, Chia-Ching (Wu, Chia-Ching.) [2] | Li, Hsin-Hua (Li, Hsin-Hua.) [3] | Yang, Cheng-Fu (Yang, Cheng-Fu.) [4]

Indexed by:

SCIE

Abstract:

In this study, [Sr0.99Eu0.01](3)MgSi2O8 phosphors were sintered at 1200-1400 degrees C for 1-5 h by using the solid-state reaction method. The crystallinity and morphology of these phosphors were characterized through X-ray diffraction analysis and field-emission scanning electron microscopy, respectively, to determine their luminescence. The photoluminescence properties, including the excitation and emission properties, of the prepared phosphors were investigated through fluorescence spectrophotometry. The alpha-Sr2SiO4, Sr2MgSi2O7, and Sr3MgSi2O8 phases coexisted in the [Sr0.99Eu0.01](3)MgSi2O8 phosphors, which were synthesized at low temperatures. The particles of these phosphors had many fine hairs on their surface and resembled Clavularia viridis, which is a coral species. Transmission electron microscopy and energy dispersive X-ray spectroscopy indicated that the fine hairs contained the Sr2SiO4 and Sr2MgSi2O7 phases. However, when the [Sr0.99Eu0.01](3)MgSi2O8 phosphors were sintered at 1400 degrees C, the Sr3MgSi2O8 phase was observed, and the Eu2+-doped Sr3MgSi2O8 phase dominated the only broad emission band, which had a central wavelength of 457 nm (blue light). The emission peaks at this wavelength were attributed to the 4f(6)5d(1)-4f(7) transition at the Sr2+(I) site, where Sr2+ was substituted by Eu2+. The average decay time of the synthesized phosphors was calculated to be 1.197 ms. The aforementioned results indicate that [Sr0.99Eu0.01](3)MgSi2O8 can be used as a blue-emitting phosphor in ultraviolet-excited white light-emitting diodes.

Keyword:

blue emission Eu2O3 phosphor Sr3MgSi2O8

Community:

  • [ 1 ] [Lee, Chou-Yuan]Fuzhou Univ Int Studies & Trade, Sch Big Data, Fuzhou 350202, Peoples R China
  • [ 2 ] [Wu, Chia-Ching]Natl Taitung Univ, Dept Appl Sci, Taitung 95092, Taiwan
  • [ 3 ] [Li, Hsin-Hua]Natl Univ Kaohsiung, Dept Chem & Mat Engn, Kaohsiung 811726, Taiwan
  • [ 4 ] [Yang, Cheng-Fu]Natl Univ Kaohsiung, Dept Chem & Mat Engn, Kaohsiung 811726, Taiwan
  • [ 5 ] [Yang, Cheng-Fu]Chaoyang Univ Technol, Dept Aeronaut Engn, Taichung 413310, Taiwan

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Source :

NANOMATERIALS

ISSN: 2079-4991

Year: 2022

Issue: 15

Volume: 12

5 . 3

JCR@2022

4 . 4 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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