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author:

Fan, Huizhou (Fan, Huizhou.) [1] | Duan, song (Duan, song.) [2] | Hong, Ruoyu (Hong, Ruoyu.) [3] | Xu, Ying (Xu, Ying.) [4]

Indexed by:

EI

Abstract:

In this study, the ferrocene modified polyaniline [P(FcA-co-ANI)] with tunable electrical conductivity was prepared by introducing ferrocene groups into the main chain of polyaniline (PANI) with a hydrochloric acid dopant. The 1H NMR, SEM, XRD and FT-IR results proved the successful preparation of the copolymers P(FcA-co-ANI). The corrosion resistance of the coatings on Q215 steel was investigated by EIS. The results showed that the P(FcA-co-ANI)/EP coatings and PANI/EP coatings all improved the long-term corrosion resistance by more than 2 orders of magnitude with comparison of EP coatings. Both coatings showed excellent corrosion inhibition. Furthermore, the |Z|0.01 Hz values of the P(FcA-co-ANI)/EP coating started to recover in a shorter period of time and returned to higher values compared to the PANI/EP coating, and did not drop as sharply as the PANI/EP coating in the later stages of immersion. Besides, the results of Rc and Rct values also show that the P(FcA-co-ANI)/EP coatings provide faster and better corrosion inhibition. This is due to the greater conductivity P(FcA-co-ANI) being more sensitive to the electrons generated by metal corrosion and so generating the passivation layer faster. The impact and peel tests show excellent mechanical properties and adhesion of the coating. This work offers some theoretical help for understanding the anticorrosion mechanism of PANI. © 2022

Keyword:

Aniline Corrosion inhibitors Corrosion resistance Corrosion resistant coatings Electric conductivity Electrochemical corrosion Epoxy resins Iron compounds Organometallics Passivation Polyaniline Steel corrosion

Community:

  • [ 1 ] [Fan, Huizhou]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Duan, song]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 3 ] [Hong, Ruoyu]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Xu, Ying]College of Chemical Engineering, Fuzhou University, Fuzhou; 350108, China

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Source :

Progress in Organic Coatings

ISSN: 0300-9440

Year: 2022

Volume: 172

6 . 6

JCR@2022

6 . 5 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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